Photocatalytic Degradation of Tetracycline by Z-Scheme Bi2WO6/ZIF-8

• Published in: Journal of inorganic and organometallic polymers and materials 2022-07, Vol.32 (7), p.2371-2383
• Main Authors: Dai, Xiaojun, Feng, Sheng, Wu, Wei, Zhou, Yun, Ye, Zhiwei, Wang, Yang, Cao, Xun
• Format: Article
• Language: English
• Subjects: Anions; Bismuth compounds; Catalysis; Catalytic activity; Chemistry; Chemistry and Materials Science; Composite materials; Heterojunctions; Inorganic Chemistry; Organic Chemistry; Photocatalysis; Photodegradation; Polymer Sciences; Tungstates; Ultraviolet radiation
• ISSN: 1574-1443; 1574-1451
• DOI: 10.1007/s10904-022-02273-5

To improve the photocatalytic activity of Bi 2 WO 6 , ZIF-8 was successfully introduced with the in-situ growth for the first time. The addition of ZIF-8 effectively inhibited the recombination of photogenerated electron–hole pairs with further improved electron utilization efficiency. The superoxide anion, .O 2 − , generated, greatly improved the photocatalytic activity. The performance of Bi 2 WO 6 /ZIF-8 in the photodegradation of tetracycline (TC) was studied under different conditions, including the proportions of ZIF-8, the dosage of catalyst, and the concentration of TC. The results indicated that 10 mg of B/Z/5/1 offered the best photocatalytic activity under UV light, achieving 97.8% degradation of TC (20 mg/L) within 80 min. The measured rate constant (k) for TC degradation was almost 3 times that of pure Bi 2 WO 6 . The effects of pH, HA, and inorganic anions on the degradation of TC were also studied for the simulated real water. Further, B/Z/5/1 could be reutilized up to five cycles without reduction of the catalysis performance. Therefore, the Bi 2 WO 6 /ZIF-8 heterojunction composite material can be utilized as an efficient photocatalyst for remediation of environmental pollution.