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Thermal analysis of materials based on calcium sulphate derived from various sources
The paper presents and discusses the results of raw materials investigations based on calcium sulphate derived from various origins. The aim of these investigations was the evaluation of perspectives of using flue gas desulfurization gypsum (FGDG) as a potential raw material in the fertilizer indust...
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Published in: | Journal of thermal analysis and calorimetry 2022-09, Vol.147 (18), p.9923-9934 |
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container_end_page | 9934 |
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creator | Myka, Agnieszka Łyszczek, Renata Zdunek, Anna Rusek, Piotr |
description | The paper presents and discusses the results of raw materials investigations based on calcium sulphate derived from various origins. The aim of these investigations was the evaluation of perspectives of using flue gas desulfurization gypsum (FGDG) as a potential raw material in the fertilizer industry, in comparison with the currently applied raw materials and others (anhydrite, natural gypsum, phosphogypsum, synthetic building plaster). To preview a new potential industrial application of FGDG, the investigations were focused on thermal analysis (thermogravimetry, differential scanning calorimetry) coupled with mass spectrometry, X-ray fluorescence, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectroscopy. The chemical composition and thermal analysis of FGD gypsums in comparison with other samples based on CaSO
4
revealed their high purity with low concentration of impurities and heavy metals. Only for one FGDG sample, the concentration of mercury exceeded the acceptable limit. The FGD gypsums seem to be attractive raw materials in the fertilizer industry. |
doi_str_mv | 10.1007/s10973-022-11319-2 |
format | article |
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4
revealed their high purity with low concentration of impurities and heavy metals. Only for one FGDG sample, the concentration of mercury exceeded the acceptable limit. The FGD gypsums seem to be attractive raw materials in the fertilizer industry.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-022-11319-2</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Agricultural chemicals ; Analysis ; Analytical Chemistry ; Calcium sulfate ; Calorimetry ; Chemical composition ; Chemistry ; Chemistry and Materials Science ; Coal-fired power plants ; Emission analysis ; Fertilizer industry ; Fertilizers ; Flue gas desulfurization gypsum ; Fourier transforms ; Gypsum ; Heavy metals ; Inductively coupled plasma ; Industrial applications ; Infrared spectroscopy ; Inorganic Chemistry ; Mass spectrometry ; Measurement Science and Instrumentation ; Optical emission spectroscopy ; Phosphogypsum ; Physical Chemistry ; Polymer Sciences ; Raw materials ; Thermal analysis ; Thermogravimetry ; X-ray fluorescence ; X-ray spectroscopy</subject><ispartof>Journal of thermal analysis and calorimetry, 2022-09, Vol.147 (18), p.9923-9934</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2022</rights><rights>COPYRIGHT 2022 Springer</rights><rights>Akadémiai Kiadó, Budapest, Hungary 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-3070610b2696500e5bec98589a3c2c7e4e2fcf5c8dd6ff8bb8cf4b78bf476e323</citedby><cites>FETCH-LOGICAL-c392t-3070610b2696500e5bec98589a3c2c7e4e2fcf5c8dd6ff8bb8cf4b78bf476e323</cites><orcidid>0000-0002-5797-0812</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Myka, Agnieszka</creatorcontrib><creatorcontrib>Łyszczek, Renata</creatorcontrib><creatorcontrib>Zdunek, Anna</creatorcontrib><creatorcontrib>Rusek, Piotr</creatorcontrib><title>Thermal analysis of materials based on calcium sulphate derived from various sources</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The paper presents and discusses the results of raw materials investigations based on calcium sulphate derived from various origins. The aim of these investigations was the evaluation of perspectives of using flue gas desulfurization gypsum (FGDG) as a potential raw material in the fertilizer industry, in comparison with the currently applied raw materials and others (anhydrite, natural gypsum, phosphogypsum, synthetic building plaster). To preview a new potential industrial application of FGDG, the investigations were focused on thermal analysis (thermogravimetry, differential scanning calorimetry) coupled with mass spectrometry, X-ray fluorescence, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectroscopy. The chemical composition and thermal analysis of FGD gypsums in comparison with other samples based on CaSO
4
revealed their high purity with low concentration of impurities and heavy metals. Only for one FGDG sample, the concentration of mercury exceeded the acceptable limit. The FGD gypsums seem to be attractive raw materials in the fertilizer industry.</description><subject>Agricultural chemicals</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Calcium sulfate</subject><subject>Calorimetry</subject><subject>Chemical composition</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coal-fired power plants</subject><subject>Emission analysis</subject><subject>Fertilizer industry</subject><subject>Fertilizers</subject><subject>Flue gas desulfurization gypsum</subject><subject>Fourier transforms</subject><subject>Gypsum</subject><subject>Heavy metals</subject><subject>Inductively coupled plasma</subject><subject>Industrial applications</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Mass spectrometry</subject><subject>Measurement Science and Instrumentation</subject><subject>Optical emission spectroscopy</subject><subject>Phosphogypsum</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Raw materials</subject><subject>Thermal analysis</subject><subject>Thermogravimetry</subject><subject>X-ray fluorescence</subject><subject>X-ray spectroscopy</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kV1L5TAQhous4Ocf8CrglRc9O0lOmuZSZP0AYWE9Xoc0nRwrbXPMtLL-e6MVFm-WuZgh87zDG96iOOOw4gD6J3EwWpYgRMm55KYUe8UhV3VdCiOqH3mWea64goPiiOgZAIwBflhsNk-YBtczN7r-jTpiMbDBTZg61xNrHGHL4si86303D4zmfveU16zNxGvehRQH9upSF2diFOfkkU6K_ZDVePrVj4vH61-bq9vy_vfN3dXlfemlEVMpQUPFoRGVqRQAqga9qVVtnPTCa1yjCD4oX7dtFULdNLUP60bXTVjrCqWQx8X5cneX4suMNNnnbCB_hKzQoLSWGmSmVgu1dT3abgxxSs7nanHofBwxdPn9UnPFleGwzoKLb4LMTPh32rqZyN49_PnOioX1KRIlDHaXusGlN8vBfkRjl2hsjsZ-RmM_fMtFRBket5j--f6P6h1CFZDR</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Myka, Agnieszka</creator><creator>Łyszczek, Renata</creator><creator>Zdunek, Anna</creator><creator>Rusek, Piotr</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><orcidid>https://orcid.org/0000-0002-5797-0812</orcidid></search><sort><creationdate>20220901</creationdate><title>Thermal analysis of materials based on calcium sulphate derived from various sources</title><author>Myka, Agnieszka ; Łyszczek, Renata ; Zdunek, Anna ; Rusek, Piotr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-3070610b2696500e5bec98589a3c2c7e4e2fcf5c8dd6ff8bb8cf4b78bf476e323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Agricultural chemicals</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Calcium sulfate</topic><topic>Calorimetry</topic><topic>Chemical composition</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coal-fired power plants</topic><topic>Emission analysis</topic><topic>Fertilizer industry</topic><topic>Fertilizers</topic><topic>Flue gas desulfurization gypsum</topic><topic>Fourier transforms</topic><topic>Gypsum</topic><topic>Heavy metals</topic><topic>Inductively coupled plasma</topic><topic>Industrial applications</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Mass spectrometry</topic><topic>Measurement Science and Instrumentation</topic><topic>Optical emission spectroscopy</topic><topic>Phosphogypsum</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Raw materials</topic><topic>Thermal analysis</topic><topic>Thermogravimetry</topic><topic>X-ray fluorescence</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Myka, Agnieszka</creatorcontrib><creatorcontrib>Łyszczek, Renata</creatorcontrib><creatorcontrib>Zdunek, Anna</creatorcontrib><creatorcontrib>Rusek, Piotr</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Myka, Agnieszka</au><au>Łyszczek, Renata</au><au>Zdunek, Anna</au><au>Rusek, Piotr</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal analysis of materials based on calcium sulphate derived from various sources</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>147</volume><issue>18</issue><spage>9923</spage><epage>9934</epage><pages>9923-9934</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>The paper presents and discusses the results of raw materials investigations based on calcium sulphate derived from various origins. The aim of these investigations was the evaluation of perspectives of using flue gas desulfurization gypsum (FGDG) as a potential raw material in the fertilizer industry, in comparison with the currently applied raw materials and others (anhydrite, natural gypsum, phosphogypsum, synthetic building plaster). To preview a new potential industrial application of FGDG, the investigations were focused on thermal analysis (thermogravimetry, differential scanning calorimetry) coupled with mass spectrometry, X-ray fluorescence, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectroscopy. The chemical composition and thermal analysis of FGD gypsums in comparison with other samples based on CaSO
4
revealed their high purity with low concentration of impurities and heavy metals. Only for one FGDG sample, the concentration of mercury exceeded the acceptable limit. The FGD gypsums seem to be attractive raw materials in the fertilizer industry.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-022-11319-2</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-5797-0812</orcidid></addata></record> |
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subjects | Agricultural chemicals Analysis Analytical Chemistry Calcium sulfate Calorimetry Chemical composition Chemistry Chemistry and Materials Science Coal-fired power plants Emission analysis Fertilizer industry Fertilizers Flue gas desulfurization gypsum Fourier transforms Gypsum Heavy metals Inductively coupled plasma Industrial applications Infrared spectroscopy Inorganic Chemistry Mass spectrometry Measurement Science and Instrumentation Optical emission spectroscopy Phosphogypsum Physical Chemistry Polymer Sciences Raw materials Thermal analysis Thermogravimetry X-ray fluorescence X-ray spectroscopy |
title | Thermal analysis of materials based on calcium sulphate derived from various sources |
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