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A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties
A new compound, [ Cl(2,2'-Bipy) 4 ]{[Cu II (2,2'-Bipy) 2 ][ O 40 ]}·2H 2 O ( I ) (2,2'-Bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric (TG...
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| Published in: | Russian journal of coordination chemistry 2022-09, Vol.48 (9), p.592-599 |
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| Main Authors: | , , , , , |
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| cites | cdi_FETCH-LOGICAL-c316t-c29af4979fa31bd49cc472ed08dc75f332033e9d6c823f9b4a6603857642edf33 |
| container_end_page | 599 |
| container_issue | 9 |
| container_start_page | 592 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 48 |
| creator | Liu, Y. B. Zheng, J. J. Tian, G. Wang, H. Alating, S. G. Nie, J. S. |
| description | A new compound, [
Cl(2,2'-Bipy)
4
]{[Cu
II
(2,2'-Bipy)
2
][
O
40
]}·2H
2
O (
I
) (2,2'-Bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric (TG) analysis, power X-ray diffraction (PXRD) and X-ray single-crystal diffraction analysis (CCDC no. 1936106). Compound
I
consists of a Keggin polyoxotungstate mono-supported Cu
II
-2,2'-Bipy complex, a dinuclear Cl-bridged Cu(II) complex and two water molecules. The [
Cl(2,2'-Bipy)
4
]
3+
unit is a counter ion which is anchored to the polyanion via non-covalent intermolecular interaction. In addition, the fluorescence and both the catalytic performance for the epoxidation styrene and the photocatalytic property for degradation of Rhodamine B (RhB), Methylene blue (MB) and RhB + MB aqueous solutions under UV irradiation of compound
I
have been investigated and shown good properties. |
| doi_str_mv | 10.1134/S1070328422090020 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2711395946</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2711395946</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-c29af4979fa31bd49cc472ed08dc75f332033e9d6c823f9b4a6603857642edf33</originalsourceid><addsrcrecordid>eNp1kMtKxDAYhYsoeH0AdwE3ClZz6bSNO6deZnBQYXRdMunfGukkNUlxxsfwic04ggtxlR_O953AiaJDgs8IYcn5lOAMM5onlGKOMcUb0Q5JcR4zRvLNcIc4XuXb0a5zrxgTjAd8J_q8RPfwjqZ9Z8XctCD7Vlg0Ws6sqtBQOKiQ0egOmkZp9GjapVkY3-vGeeHBIaErdKV0L1sIWtHGw-A1QSr64_H4BBVm3rWwuEDTpfYv4JQ7RcWLsEJ6sOpDeGX06XfLozUdWK_A7UdbtWgdHPy8e9HzzfVTMYonD7fj4nISS0ZSH0vKRZ3wjNeCkVmVcCmTjEKF80pmg5oxihkDXqUyp6zms0SkKWb5IEuTQIV8Lzpa93bWvPXgfPlqeqvDlyXNwqh8wJM0UGRNSWucs1CXnVVzYZclweVq-vLP9MGha8cFVjdgf5v_l74AlGGGBg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2711395946</pqid></control><display><type>article</type><title>A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties</title><source>Springer Link</source><creator>Liu, Y. B. ; Zheng, J. J. ; Tian, G. ; Wang, H. ; Alating, S. G. ; Nie, J. S.</creator><creatorcontrib>Liu, Y. B. ; Zheng, J. J. ; Tian, G. ; Wang, H. ; Alating, S. G. ; Nie, J. S.</creatorcontrib><description>A new compound, [
Cl(2,2'-Bipy)
4
]{[Cu
II
(2,2'-Bipy)
2
][
O
40
]}·2H
2
O (
I
) (2,2'-Bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric (TG) analysis, power X-ray diffraction (PXRD) and X-ray single-crystal diffraction analysis (CCDC no. 1936106). Compound
I
consists of a Keggin polyoxotungstate mono-supported Cu
II
-2,2'-Bipy complex, a dinuclear Cl-bridged Cu(II) complex and two water molecules. The [
Cl(2,2'-Bipy)
4
]
3+
unit is a counter ion which is anchored to the polyanion via non-covalent intermolecular interaction. In addition, the fluorescence and both the catalytic performance for the epoxidation styrene and the photocatalytic property for degradation of Rhodamine B (RhB), Methylene blue (MB) and RhB + MB aqueous solutions under UV irradiation of compound
I
have been investigated and shown good properties.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328422090020</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Chemistry ; Chemistry and Materials Science ; Epoxidation ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Methylene blue ; Photodegradation ; Photoelectrons ; Physical Chemistry ; Polyelectrolytes ; Rhodamine ; Single crystals ; Spectroscopic analysis ; Ultraviolet radiation ; X ray photoelectron spectroscopy</subject><ispartof>Russian journal of coordination chemistry, 2022-09, Vol.48 (9), p.592-599</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2022, Vol. 48, No. 9, pp. 592–599. © Pleiades Publishing, Ltd., 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-c29af4979fa31bd49cc472ed08dc75f332033e9d6c823f9b4a6603857642edf33</citedby><cites>FETCH-LOGICAL-c316t-c29af4979fa31bd49cc472ed08dc75f332033e9d6c823f9b4a6603857642edf33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Liu, Y. B.</creatorcontrib><creatorcontrib>Zheng, J. J.</creatorcontrib><creatorcontrib>Tian, G.</creatorcontrib><creatorcontrib>Wang, H.</creatorcontrib><creatorcontrib>Alating, S. G.</creatorcontrib><creatorcontrib>Nie, J. S.</creatorcontrib><title>A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>A new compound, [
Cl(2,2'-Bipy)
4
]{[Cu
II
(2,2'-Bipy)
2
][
O
40
]}·2H
2
O (
I
) (2,2'-Bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric (TG) analysis, power X-ray diffraction (PXRD) and X-ray single-crystal diffraction analysis (CCDC no. 1936106). Compound
I
consists of a Keggin polyoxotungstate mono-supported Cu
II
-2,2'-Bipy complex, a dinuclear Cl-bridged Cu(II) complex and two water molecules. The [
Cl(2,2'-Bipy)
4
]
3+
unit is a counter ion which is anchored to the polyanion via non-covalent intermolecular interaction. In addition, the fluorescence and both the catalytic performance for the epoxidation styrene and the photocatalytic property for degradation of Rhodamine B (RhB), Methylene blue (MB) and RhB + MB aqueous solutions under UV irradiation of compound
I
have been investigated and shown good properties.</description><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Epoxidation</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Methylene blue</subject><subject>Photodegradation</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Polyelectrolytes</subject><subject>Rhodamine</subject><subject>Single crystals</subject><subject>Spectroscopic analysis</subject><subject>Ultraviolet radiation</subject><subject>X ray photoelectron spectroscopy</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAYhYsoeH0AdwE3ClZz6bSNO6deZnBQYXRdMunfGukkNUlxxsfwic04ggtxlR_O953AiaJDgs8IYcn5lOAMM5onlGKOMcUb0Q5JcR4zRvLNcIc4XuXb0a5zrxgTjAd8J_q8RPfwjqZ9Z8XctCD7Vlg0Ws6sqtBQOKiQ0egOmkZp9GjapVkY3-vGeeHBIaErdKV0L1sIWtHGw-A1QSr64_H4BBVm3rWwuEDTpfYv4JQ7RcWLsEJ6sOpDeGX06XfLozUdWK_A7UdbtWgdHPy8e9HzzfVTMYonD7fj4nISS0ZSH0vKRZ3wjNeCkVmVcCmTjEKF80pmg5oxihkDXqUyp6zms0SkKWb5IEuTQIV8Lzpa93bWvPXgfPlqeqvDlyXNwqh8wJM0UGRNSWucs1CXnVVzYZclweVq-vLP9MGha8cFVjdgf5v_l74AlGGGBg</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Liu, Y. B.</creator><creator>Zheng, J. J.</creator><creator>Tian, G.</creator><creator>Wang, H.</creator><creator>Alating, S. G.</creator><creator>Nie, J. S.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220901</creationdate><title>A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties</title><author>Liu, Y. B. ; Zheng, J. J. ; Tian, G. ; Wang, H. ; Alating, S. G. ; Nie, J. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-c29af4979fa31bd49cc472ed08dc75f332033e9d6c823f9b4a6603857642edf33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Epoxidation</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Methylene blue</topic><topic>Photodegradation</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Polyelectrolytes</topic><topic>Rhodamine</topic><topic>Single crystals</topic><topic>Spectroscopic analysis</topic><topic>Ultraviolet radiation</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Y. B.</creatorcontrib><creatorcontrib>Zheng, J. J.</creatorcontrib><creatorcontrib>Tian, G.</creatorcontrib><creatorcontrib>Wang, H.</creatorcontrib><creatorcontrib>Alating, S. G.</creatorcontrib><creatorcontrib>Nie, J. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Y. B.</au><au>Zheng, J. J.</au><au>Tian, G.</au><au>Wang, H.</au><au>Alating, S. G.</au><au>Nie, J. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>48</volume><issue>9</issue><spage>592</spage><epage>599</epage><pages>592-599</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>A new compound, [
Cl(2,2'-Bipy)
4
]{[Cu
II
(2,2'-Bipy)
2
][
O
40
]}·2H
2
O (
I
) (2,2'-Bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal gravimetric (TG) analysis, power X-ray diffraction (PXRD) and X-ray single-crystal diffraction analysis (CCDC no. 1936106). Compound
I
consists of a Keggin polyoxotungstate mono-supported Cu
II
-2,2'-Bipy complex, a dinuclear Cl-bridged Cu(II) complex and two water molecules. The [
Cl(2,2'-Bipy)
4
]
3+
unit is a counter ion which is anchored to the polyanion via non-covalent intermolecular interaction. In addition, the fluorescence and both the catalytic performance for the epoxidation styrene and the photocatalytic property for degradation of Rhodamine B (RhB), Methylene blue (MB) and RhB + MB aqueous solutions under UV irradiation of compound
I
have been investigated and shown good properties.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328422090020</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3284 |
| ispartof | Russian journal of coordination chemistry, 2022-09, Vol.48 (9), p.592-599 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_2711395946 |
| source | Springer Link |
| subjects | Aqueous solutions Chemistry Chemistry and Materials Science Epoxidation Infrared analysis Infrared spectroscopy Inorganic Chemistry Methylene blue Photodegradation Photoelectrons Physical Chemistry Polyelectrolytes Rhodamine Single crystals Spectroscopic analysis Ultraviolet radiation X ray photoelectron spectroscopy |
| title | A New Supramolecular Hybrid Based on Keggin Polyoxotungstates and Dinuclear Cl-Bridged Cu(II) Complex: Synthesis, Characterization, and Properties |
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