Microstructure and mechanical properties of WC–(Ti, M)(C, N)–Co cemented carbides with different nitrogen contents

• Published in: Rare metals 2022-10, Vol.41 (10), p.3530-3538
• Main Authors: Fan, Han-Jie, Liu, Ying, Ye, Jin-Wen, Qiu, Wei-Bin, Qiu, Yu-Chong
• Format: Article
• Language: English
• Subjects: Biomaterials; Carbon nitride; Cemented carbides; Chemistry and Materials Science; Energy; Grain growth; Grain size; Heat treating; Hot isostatic pressing; Materials Engineering; Materials Science; Mechanical properties; Metallic Materials; Microstructure; Nanoscale Science and Technology; Nitrogen; Physical Chemistry; Solid solutions; Titanium; Tungsten carbide
• ISSN: 1001-0521; 1867-7185
• DOI: 10.1007/s12598-016-0737-0

Three kinds of (Ti, M)(C 1− x , N x ) (M = Ta, Nb, W) quaternary solid-solution powders with various nitrogen contents were synthesized by carbothermal reduction–nitridation (CRN) process. Effect of nitrogen content on the microstructure and mechanical properties of WC–(Ti, M)(C 1− x , N x )–Co cemented carbides fabricated by sinter-hot isostatic pressing (HIP) were systematically investigated in this paper. The results show that the nitrogen content in the carbonitride raw powders strongly influences the morphology, the grain size and the compositions of the cemented carbides. All the cemented carbides with different nitrogen contents have a similar microstructural appearance: weak core–rim structure consisting of solid-solution phase embedded in WC–Co system. It is also observed that the carbonitride solid solution could somewhat reduce the WC grain growth, and the effectiveness of refining and the rim thickness are sensitively related to the nitrogen content of (Ti, M)(C 1− x , N x ) solid solutions. In addition, with an increase in the nitrogen content, mechanical properties of these hard metals are enhanced, which were discussed in terms of the constituent, the microstructure and the solution behavior of the carbonitride solid solutions.