The polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs

The novel polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs has been developed to prepare 2-pyrrolidinone derivatives with polychloromethyl units with the use of an inexpensive copper salt under mild conditions. This strategy includes...

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Published in:Organic & biomolecular chemistry 2022-09, Vol.2 (35), p.767-77
Main Authors: Zhang, Jun-Hao, Jiang, Li-Lin, Hu, Sen-Jie, Li, Jiao-Zhe, Yu, Xuan-Chi, Liu, Fa-Liang, Guan, Yu-Tao, Lei, Ke-Wei, Wei, Wen-Ting
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Language:English
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Organochlorine compounds
Peroxides
Substrates
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cited_by cdi_FETCH-LOGICAL-c244t-fca3dcce237bcdcc0eff80e342e8cd18e049bc0c37e8b3e24d4caaf0d358c55c3
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container_title Organic & biomolecular chemistry
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creator Zhang, Jun-Hao
Jiang, Li-Lin
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Wei, Wen-Ting
description The novel polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs has been developed to prepare 2-pyrrolidinone derivatives with polychloromethyl units with the use of an inexpensive copper salt under mild conditions. This strategy includes two dual-role designs, not only improving atomic utilization but also allowing a cleaner process. The wide substrate scope and simple reaction conditions demonstrate the practicability of this protocol. The novel polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs has been developed with the use of an inexpensive copper salt under mild conditions.
doi_str_mv 10.1039/d2ob01330d
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Organochlorine compounds
Peroxides
Substrates
title The polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs
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