Effect of CO2 on activity and coke formation over gallium-based catalysts for propane dehydrogenation

• Published in: Applied catalysis. A, General General, 2022-08, Vol.643, p.118795, Article 118795
• Main Authors: Zhang, Yaoyuan, Aly, Mostafa
• Format: Article
• Language: English
• Subjects: Activity; Ammonia; Carbon dioxide; Catalysts; CO2 effect; Coke; Coke formation; Conversion; Dehydrogenation; Gallium; Gallium-based catalysts; Propane; Propane dehydrogenation; Selectivity
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2022.118795

This work investigated the effects of support and CO2 co-feeding on the activity and coke formation over gallium-based catalysts for propane dehydrogenation (PDH). The prepared catalysts were characterized by XRD, NH3-TPD, CO2-TPD, O2-TPO, pyridine-IR, Raman and tested in CO2 assisted propane dehydrogenation. The results revealed Ga/HZSM-5 as a highly active and carbon resistant catalyst, more so in the presence of CO2. The structure of coke species was investigated and found to be different over these gallium based catalysts as characterized by O2-TPO and Raman techniques. Coke formation behavior is shown to be directly related to the acid density and strength as well as the topological structure of the support. Moreover, the introduction of CO2 leads to an increase in propane conversion and a decrease in coke selectivity over Ga/HZSM-5 catalysts, although coke species become more graphitic in nature. Lastly, PDH reaction with different co-feeding agents (H2, CO2 and O2) were performed and the results indicate CO2 co-feeding yields the highest propane conversion and lower coke deposition, exhibiting a good application prospect. [Display omitted] •The activity and coke formation of gallium based catalysts strongly depend on the support.•The introduction of CO2 helps to decrease the deactivation rate during propane dehydrogenation.•Carbon deposits in the presence of CO2 are more graphitic in nature.