Effect of Nano‐Copper Chromite on the Thermal Decomposition and Combustion of AP‐Based Solid Propellants

This investigation was devoted to exploring the application performance of nano‐combustion catalyst CuCr2O4 in solid propellants. In this paper, raw CuCr2O4 and nano‐CuCr2O4 prepared by the mechanical grinding method were applied in solid propellants containing ammonium perchlorate (AP), which are a...

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Bibliographic Details
Published in:Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2022-10, Vol.47 (10), p.n/a
Main Authors: Gou, Bingwang, Kou, Yong, Hu, Yubing, Zhang, Guangpu, Guo, Hu, Xiao, Lei, Zhao, Fengqi, Gao, Hongxu, Jiang, Wei, Hao, Gazi
Format: Article
Language:English
Subjects:
Ammonium perchlorates
AP/CMDB propellant
AP/HTPB propellant
Burning rate
Chromite
Combustion
Decomposition
Heat of formation
HTPB propellants
Nano-CuCr2O4
Polybutadiene
Solid propellants
Thermal decomposition
Thermogravimetric analysis
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Summary:This investigation was devoted to exploring the application performance of nano‐combustion catalyst CuCr2O4 in solid propellants. In this paper, raw CuCr2O4 and nano‐CuCr2O4 prepared by the mechanical grinding method were applied in solid propellants containing ammonium perchlorate (AP), which are ammonium perchlorate/ hydroxy‐terminated polybutadiene propellant (AP/HTPB) and ammonium perchlorate/composite modified double‐base propellant (AP/CMDB). And the scanning electron microscope, displacement volume method, thermogravimetric analysis, differential scanning calorimetry, and strand burner method were employed to characterize the performance of AP‐based solid propellants. The results show that the AP/HTPB propellant has fewer defects on the surface of it due to the presence of nano‐CuCr2O4, but it has no significant effect on the AP/CMDB propellant. Nano‐CuCr2O4 can also significantly increase the density of AP/HTPB propellant and AP/CMDB propellant to 1.736 g/cm3 and 1.633 g/cm3, respectively. Nano‐CuCr2O4 obviously advances the decomposition temperature of AP/HTPB propellant and AP/CMDB propellant, which also increases the apparent heat of decomposition. In addition, the burning rate of nano‐CuCr2O4‐AP/HTPB propellant and nano‐CuCr2O4‐AP/CMDB propellant increased to 1.60 mm/s and 3.23 mm/s, with an increase of 28.3 % and 26.3 %, respectively. Therefore, nano‐CuCr2O4 is expected to be widely used in solid propellants due to its excellent properties.
ISSN:0721-3115
1521-4087
DOI:10.1002/prep.202200087