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Enhancement of magnetic and dielectrics performance of BaFe2O4 nanoparticles influenced by tri-sodium citrate as surfactant

The barium ferrite (BaFe 2 O 4 ) nanoparticles (NPs) were synthesized with the self-burning process using different molar ratios of tri-sodium citrate. Structural, morphological, magnetic, and dielectrics performance of BaFe 2 O 4 NPs were analyzed by XRD, FESEM, VSM and impedance spectroscopy chara...

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Published in:Journal of materials science. Materials in electronics 2022-10, Vol.33 (30), p.23841-23850
Main Authors: Dilip, R., Ravikumar, K., Chandekar, Kamlesh V., Shkir, Mohd, Krishnan, V. Gopala, Shinde, Keshav S., Ashraf, I. M.
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creator Dilip, R.
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description The barium ferrite (BaFe 2 O 4 ) nanoparticles (NPs) were synthesized with the self-burning process using different molar ratios of tri-sodium citrate. Structural, morphological, magnetic, and dielectrics performance of BaFe 2 O 4 NPs were analyzed by XRD, FESEM, VSM and impedance spectroscopy characterizations. The formation of BaFe 2 O 4 NPs was confirmed by XRD patterns with the prominent orientation at (212) planes. Fourier transform infrared spectroscopy spectra were observed at 770 cm −1 transforms the formation of BaFe 2 O 4 . The influence of different molar ratios of tri-sodium citrate, the morphology has changed from common agglomerated platelets shaped into mixed spherical/rod shaped, which is visualized by Field emission Scanning Electron microscopy. Magnetic properties of BeFe 2 O 4 NPs were confirmed by vibrating sample magnetometer and the prepared NPs induced ferromagnetic behavior due to inverse particle size effects. Dielectric constant and loss values of the prepared NPs were enhanced from 45.11 to 86.41 and from 3.21 to 4.81, respectively, which indicate changing the shape and size of the BaFe 2 O 4 NPs.
doi_str_mv 10.1007/s10854-022-09142-4
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subjects Barium hexaferrite
Characterization and Evaluation of Materials
Chemistry and Materials Science
Ferromagnetism
Field emission microscopy
Fourier transforms
Infrared spectra
Infrared spectroscopy
Magnetic properties
Magnetometers
Materials Science
Morphology
Nanoparticles
Optical and Electronic Materials
Size effects
Sodium citrate
Spectrum analysis
title Enhancement of magnetic and dielectrics performance of BaFe2O4 nanoparticles influenced by tri-sodium citrate as surfactant
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