Lactide-derived monomers for radical thiocarbonyl addition ring-opening copolymerisation

The six-membered dl -thionolactide and dl -dithionolactide are reactive in radical ring-opening copolymerisation with a series of vinyl monomers to yield chemically degradable polymers. Bleach is an excellent degrading agent for both thioester and thioacetal linkages compared to classical nucleophil...

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Bibliographic Details
Published in:Polymer chemistry 2022-10, Vol.13 (39), p.5525-5529
Main Authors: Ivanchenko, Oleksandr, Mazières, Stéphane, Harrisson, Simon, Destarac, Mathias
Format: Article
Language:English
Subjects:
Amines
Bleaches
Chemical Sciences
Copolymerization
Monomers
Polymer chemistry
Ring opening polymerization
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Summary:The six-membered dl -thionolactide and dl -dithionolactide are reactive in radical ring-opening copolymerisation with a series of vinyl monomers to yield chemically degradable polymers. Bleach is an excellent degrading agent for both thioester and thioacetal linkages compared to classical nucleophilic treatment with amines. The six-membered dl -thionolactide and dl -dithionolactide are reactive in radical ring-opening copolymerisation with a series of vinyl monomers to yield chemically degradable polymers.
ISSN:1759-9954
1759-9962
DOI:10.1039/d2py00893a