Solution processed 2D SnSe nanosheets catalysts: Temperature dependent oxygen reduction reaction performance in alkaline media

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2022-07, Vol.916, p.116381, Article 116381
• Main Authors: Feng, Zhanxiong, Jadhav, Chandradip D., Patil, Girish P., Wang, Yun, Zhang, Chuang, Baviskar, Vijay S., Jia, Zhiyong, Minnes, Refael
• Format: Article
• Language: English
• Subjects: Annealing effect; Catalysts; Charge transfer; Chemical reduction; Current density; Electrochemical analysis; Electron transfer; Electrons; Field emission microscopy; Field emission spectroscopy; Nanosheets; ORR; Oxygen reduction reactions; Photoelectrons; Reaction mechanism; SnSe; Solution chemistry; Temperature dependence; Tin selenide; X ray photoelectron spectroscopy
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2022.116381

[Display omitted] •Single phase SnSe synthesis with non-toxic Se precursor, the monetary synthetic route is employed.•The SnSe catalysts 4-electron pathway for oxygen reduction.•The current density and charge transfer number of SnSe-500 catalysts are 4.50 mA/cm2 and 3.62. One of the most effective synthesis routes is the simple solution process, which is an inexpensive way to make single phase 2-Dimensional (2D) Tin Selenide (SnSe) nanosheets. X-ray diffraction (XRD), X-ray Photoelectron spectroscopy (XPS), and Field Emission Scanning Electron Microscope (FESEM)were used to confirm the structural and topographical investigations. 2D SnSe served for Oxygen Reduction Reaction (ORR) electrochemical performance in KOH solution. Later, 2D SnSe is annealed at 300, 400 and 500 °C later termed as SnSe-300, SnSe-400 and SnSe-500 respectively to investigate the electrochemical behavior of catalyst. As the temperature increases ORR performance improved. For the first time, 2- and 4-electron transfer pathway mechanism of SnSe catalysts is discussed. As enhancement in the performance of as prepared 2D SnSe catalysts ensured with various parameters like current density, electron charge transfer number and half-wave potential. SnSe-500 has a half-wave potential of −0.75 V, which is lower than other catalysts in this case. In addition, a current density of 4.50 mA/cm2 was recorded, which is superior to other catalysts in this case.