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Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds
The standard enthalpies of formation of compounds Bi 1.2 Gd 0.8 O 3 and Bi 12.5 Nd 1.5 CoO 22.3 were determined by solution calorimetry: Δ f H 0 (Bi 1.2 Gd 0.8 O 3 , s, 298.15 K) = –849.7 ± 4.9 kJ/mol, and Δ f H 0 (Bi 12.5 Nd 1.5 CoO 22.3 , s, 298.15 K) = –5115.5 ± 15.4 kJ/mol. The lattice enthalpie...
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| Published in: | Russian journal of inorganic chemistry 2022-11, Vol.67 (11), p.1813-1817 |
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| cites | cdi_FETCH-LOGICAL-c316t-3ef77608c3ea9e8b34782c93276fd14205a089091bdd53469859b6e290381b113 |
| container_end_page | 1817 |
| container_issue | 11 |
| container_start_page | 1813 |
| container_title | Russian journal of inorganic chemistry |
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| creator | Matskevich, N. I. Semerikova, A. N. Samoshkin, D. A. Stankus, S. V. Zaitsev, V. P. Fedorov, A. A. |
| description | The standard enthalpies of formation of compounds Bi
1.2
Gd
0.8
O
3
and Bi
12.5
Nd
1.5
CoO
22.3
were determined by solution calorimetry: Δ
f
H
0
(Bi
1.2
Gd
0.8
O
3
, s, 298.15 K) = –849.7 ± 4.9 kJ/mol, and Δ
f
H
0
(Bi
12.5
Nd
1.5
CoO
22.3
, s, 298.15 K) = –5115.5 ± 15.4 kJ/mol. The lattice enthalpies of those compounds were calculated using the Born–Haber cycle. The Bi
12.5
Nd
1.5
CoO
22.3
heat capacity was measured by differential scanning calorimetry (DSC) in the temperature range 350−1000 K. This compound was shown to experience two phase transitions at temperatures above 720 K. Accordingly, it has a potential for use in the range 350–720 K. |
| doi_str_mv | 10.1134/S0036023622600988 |
| format | article |
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1.2
Gd
0.8
O
3
and Bi
12.5
Nd
1.5
CoO
22.3
were determined by solution calorimetry: Δ
f
H
0
(Bi
1.2
Gd
0.8
O
3
, s, 298.15 K) = –849.7 ± 4.9 kJ/mol, and Δ
f
H
0
(Bi
12.5
Nd
1.5
CoO
22.3
, s, 298.15 K) = –5115.5 ± 15.4 kJ/mol. The lattice enthalpies of those compounds were calculated using the Born–Haber cycle. The Bi
12.5
Nd
1.5
CoO
22.3
heat capacity was measured by differential scanning calorimetry (DSC) in the temperature range 350−1000 K. This compound was shown to experience two phase transitions at temperatures above 720 K. Accordingly, it has a potential for use in the range 350–720 K.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023622600988</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Bismuth ; Chemistry ; Chemistry and Materials Science ; Cobalt oxides ; Enthalpy ; Gadolinium ; Heat measurement ; Inorganic Chemistry ; Neodymium ; Phase transitions ; Physical Methods of Investigation</subject><ispartof>Russian journal of inorganic chemistry, 2022-11, Vol.67 (11), p.1813-1817</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2022, Vol. 67, No. 11, pp. 1813–1817. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Zhurnal Neorganicheskoi Khimii, 2022, Vol. 67, No. 11, pp. 1626–1631.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-3ef77608c3ea9e8b34782c93276fd14205a089091bdd53469859b6e290381b113</citedby><cites>FETCH-LOGICAL-c316t-3ef77608c3ea9e8b34782c93276fd14205a089091bdd53469859b6e290381b113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Matskevich, N. I.</creatorcontrib><creatorcontrib>Semerikova, A. N.</creatorcontrib><creatorcontrib>Samoshkin, D. A.</creatorcontrib><creatorcontrib>Stankus, S. V.</creatorcontrib><creatorcontrib>Zaitsev, V. P.</creatorcontrib><creatorcontrib>Fedorov, A. A.</creatorcontrib><title>Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The standard enthalpies of formation of compounds Bi
1.2
Gd
0.8
O
3
and Bi
12.5
Nd
1.5
CoO
22.3
were determined by solution calorimetry: Δ
f
H
0
(Bi
1.2
Gd
0.8
O
3
, s, 298.15 K) = –849.7 ± 4.9 kJ/mol, and Δ
f
H
0
(Bi
12.5
Nd
1.5
CoO
22.3
, s, 298.15 K) = –5115.5 ± 15.4 kJ/mol. The lattice enthalpies of those compounds were calculated using the Born–Haber cycle. The Bi
12.5
Nd
1.5
CoO
22.3
heat capacity was measured by differential scanning calorimetry (DSC) in the temperature range 350−1000 K. This compound was shown to experience two phase transitions at temperatures above 720 K. Accordingly, it has a potential for use in the range 350–720 K.</description><subject>Bismuth</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt oxides</subject><subject>Enthalpy</subject><subject>Gadolinium</subject><subject>Heat measurement</subject><subject>Inorganic Chemistry</subject><subject>Neodymium</subject><subject>Phase transitions</subject><subject>Physical Methods of Investigation</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqXwA9gisTZwthPHHiGCglTRgTIxRI7tUFd1XOxEov-ehCIxIKa703vfne4hdInhGmOa3bwAUAaEMkIYgOD8CE1wTnHKGabHaDLK6aiforMYNwBZBgWfoLfV2gTn9b6VzqqkXMsgVWeCjZ1VMfFNcmej67v1LJlL7be2tb2bJc9mQNx3K1udlL6W2y5ZflpthsHtfN_qeI5OGrmN5uKnTtHrw_2qfEwXy_lTebtIFcWsS6lpioIBV9RIYXhNs4ITJSgpWKNxRiCXwAUIXGud04wJnouaGSKAclwP30_R1WHvLviP3sSu2vg-tMPJihSEZ4LmmA8ufHCp4GMMpql2wToZ9hWGasyw-pPhwJADEwdv-27C7-b_oS9kVXGS</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Matskevich, N. I.</creator><creator>Semerikova, A. N.</creator><creator>Samoshkin, D. A.</creator><creator>Stankus, S. V.</creator><creator>Zaitsev, V. P.</creator><creator>Fedorov, A. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221101</creationdate><title>Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds</title><author>Matskevich, N. I. ; Semerikova, A. N. ; Samoshkin, D. A. ; Stankus, S. V. ; Zaitsev, V. P. ; Fedorov, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-3ef77608c3ea9e8b34782c93276fd14205a089091bdd53469859b6e290381b113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Bismuth</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt oxides</topic><topic>Enthalpy</topic><topic>Gadolinium</topic><topic>Heat measurement</topic><topic>Inorganic Chemistry</topic><topic>Neodymium</topic><topic>Phase transitions</topic><topic>Physical Methods of Investigation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matskevich, N. I.</creatorcontrib><creatorcontrib>Semerikova, A. N.</creatorcontrib><creatorcontrib>Samoshkin, D. A.</creatorcontrib><creatorcontrib>Stankus, S. V.</creatorcontrib><creatorcontrib>Zaitsev, V. P.</creatorcontrib><creatorcontrib>Fedorov, A. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matskevich, N. I.</au><au>Semerikova, A. N.</au><au>Samoshkin, D. A.</au><au>Stankus, S. V.</au><au>Zaitsev, V. P.</au><au>Fedorov, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2022-11-01</date><risdate>2022</risdate><volume>67</volume><issue>11</issue><spage>1813</spage><epage>1817</epage><pages>1813-1817</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The standard enthalpies of formation of compounds Bi
1.2
Gd
0.8
O
3
and Bi
12.5
Nd
1.5
CoO
22.3
were determined by solution calorimetry: Δ
f
H
0
(Bi
1.2
Gd
0.8
O
3
, s, 298.15 K) = –849.7 ± 4.9 kJ/mol, and Δ
f
H
0
(Bi
12.5
Nd
1.5
CoO
22.3
, s, 298.15 K) = –5115.5 ± 15.4 kJ/mol. The lattice enthalpies of those compounds were calculated using the Born–Haber cycle. The Bi
12.5
Nd
1.5
CoO
22.3
heat capacity was measured by differential scanning calorimetry (DSC) in the temperature range 350−1000 K. This compound was shown to experience two phase transitions at temperatures above 720 K. Accordingly, it has a potential for use in the range 350–720 K.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023622600988</doi><tpages>5</tpages></addata></record> |
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| subjects | Bismuth Chemistry Chemistry and Materials Science Cobalt oxides Enthalpy Gadolinium Heat measurement Inorganic Chemistry Neodymium Phase transitions Physical Methods of Investigation |
| title | Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds |
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