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Single crystal growth and magnetism of Sr3NaIrO6 and Sr3AgIrO6: tracking the J = 0 ground state of Ir5

Single crystals of Sr3NaIrO6 and Sr3AgIrO6 have been successfully grown using hydroxides flux. Sr3NaIrO6 and Sr3AgIrO6 crystallize in the K4CdCl6-type structure with the space group R-3c (No.167). Sr3NaIrO6 and Sr3AgIrO6 are electrically insulating with estimated activation gaps of 0.68 eV and 0.80...

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Published in:arXiv.org 2022-10
Main Authors: Peng-Bo, Song, Hu, Zhiwei, Su-Yang, Hsu, Jin-Ming, Chen, Jyh-Fu, Lee, Shan-Shan Miao, You-Guo, Sh, Feng, Hai L
Format: Article
Language:English
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Summary:Single crystals of Sr3NaIrO6 and Sr3AgIrO6 have been successfully grown using hydroxides flux. Sr3NaIrO6 and Sr3AgIrO6 crystallize in the K4CdCl6-type structure with the space group R-3c (No.167). Sr3NaIrO6 and Sr3AgIrO6 are electrically insulating with estimated activation gaps of 0.68 eV and 0.80 eV, respectively. Sr3NaIrO6 and Sr3AgIrO6 show paramagnetic behavior down to 2 K.
ISSN:2331-8422
DOI:10.48550/arxiv.2210.13828