A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordinatio...

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Bibliographic Details
Published in:Journal of coordination chemistry 2022-10, Vol.75 (11-14), p.1691-1701
Main Authors: Crouch, Sophie A., Davey, Patrick R.W.J., Forsyth, Craig M., Batten, Stuart R., Paterson, Brett M.
Format: Article
Language:English
Subjects:
3-D network
argentophilic
bis(thiosemicarbazone)
coordination polymer
Coordination polymers
Hydrogen bonds
Ligands
Silver
Structural analysis
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Summary:The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2022.2092845