A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordinatio...

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Published in:Journal of coordination chemistry 2022-10, Vol.75 (11-14), p.1691-1701
Main Authors: Crouch, Sophie A., Davey, Patrick R.W.J., Forsyth, Craig M., Batten, Stuart R., Paterson, Brett M.
Format: Article
Language:English
Subjects:
3-D network
argentophilic
bis(thiosemicarbazone)
coordination polymer
Coordination polymers
Hydrogen bonds
Ligands
Silver
Structural analysis
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container_end_page 1701
container_issue 11-14
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container_title Journal of coordination chemistry
container_volume 75
creator Crouch, Sophie A.
Davey, Patrick R.W.J.
Forsyth, Craig M.
Batten, Stuart R.
Paterson, Brett M.
description The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.
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subjects 3-D network
argentophilic
bis(thiosemicarbazone)
coordination polymer
Coordination polymers
Hydrogen bonds
Ligands
Silver
Structural analysis
title A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions
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