Synthesis and Nuclear Radiation Shielding Ability of Li2O-ZnO-P2O5 Glasses: The Role of Yb2O3

• Published in: Journal of electronic materials 2022-12, Vol.51 (12), p.7283-7296
• Main Authors: Saleh, Emran Eisa, Algradee, Mohammed A., Alresheedi, Faisal, Al-Fakeh, Maged S., El-Fiki, Soad A., Youssef, G. M., El Sharbini, Tharwat M.
• Format: Article
• Language: English
• Subjects: Atomic properties; Attenuation coefficients; Characterization and Evaluation of Materials; Chemistry and Materials Science; Cross-sections; Electron density; Electronics and Microelectronics; Energy absorption; Fast neutrons; Gamma rays; Instrumentation; Lithium oxides; Materials Science; Nuclear radiation; Optical and Electronic Materials; Original Research Article; Parameters; Phosphorus pentoxide; Radiation; Radiation shielding; Software; Solid State Physics; Zinc oxide
• ISSN: 0361-5235; 1543-186X
• DOI: 10.1007/s11664-022-09979-9

Nuclear radiation shielding parameters for glass samples composed of 20 mol.% Li 2 O-40 mol.% ZnO-40 mol.% P 2 O 5 : x wt.% Yb 2 O 3 ( x  = 0, 0.2, 0.4, 0.6, 0.8, 1, 2) were evaluated. The samples were synthesized using the melt-quenching technique. The prepared samples were encoded Yb0.0, Yb0.2, Yb0.4, Yb0.6, Yb0.8, Yb1 and Yb2 according to the Yb 2 O 3 content. X-ray diffraction (XRD) reveals that all the prepared samples were amorphous. The gamma ray shielding parameters such as mass attenuation coefficient (MAC), linear attenuation coefficient (LAC), half value layer (HVL) and mean free path (MFP) were obtained using Phy-X/PSD and XCOM software programs. The atomic cross section (ACS), electronic cross section (ECS), effective atomic number (Z eff ), and electron density (N eff ) were evaluated, as well as exposure buildup factor (EBF) and energy absorption buildup factor (EABF). The MAC values were found to be 26.304–31.872 cm 2 /g for Yb0.0–Yb2, respectively. The HVL and MFP values were found to be (0.008–0.007 cm) and (0.012–0.010 cm) for Yb0.0–Yb2, respectively. The ACS and ECS values were found to be (9.912 × 10 −21  cm 2 /g) up to 13.06 × 10 −21  cm 2 /g) and (3.990 × 10 −23 up to 4.900 × 10 −23  cm 2 /g) for Yb0.0–Yb2, respectively. The Z eff and N eff values were found to be (24.83–26.64) and (6.59 × 10 23 up to 6.50 × 10 23 electrons/g) for Yb0.0–Yb2, respectively. The results showed that the addition of Yb 2 O 3 improves gamma-ray shielding properties of the glass. On the other hand, adding Yb 2 O 3 to the prepared glass leads to a decrease in the removal cross section for fast neutrons (Ʃ R ) from 0.103 to 0.096 cm for Yb0.0–Yb2, respectively. The gamma-ray shielding parameters for the present samples were compared with commercial concrete and glass used as gamma ray shields.