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Symmetric supercapacitor device applications of rGO / Co3O4 / polypyrrole nanocomposites

Symmetric supercapacitor electrode design and synthesis of micro-nano structured metal oxide (Co 3 O 4 ) and polypyrrole with reduced graphene oxide (rGO) have played an important role in supercapacitor investigations. The characterizations of rGO/Co 3 O 4 /PPy nanocomposites were given by FTIR-ATR,...

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Published in:Ionics 2022-12, Vol.28 (12), p.5581-5598
Main Authors: Ates, Murat, Yoruk, Ozan, Bayrak, Yuksel
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description Symmetric supercapacitor electrode design and synthesis of micro-nano structured metal oxide (Co 3 O 4 ) and polypyrrole with reduced graphene oxide (rGO) have played an important role in supercapacitor investigations. The characterizations of rGO/Co 3 O 4 /PPy nanocomposites were given by FTIR-ATR, SEM–EDX, TGA-DTA, BET surface, and porous analysis and Four-point probe analysis. The symmetric rGO/Co 3 O 4 /PPy supercapacitor devices were presented in different initial feed ratios of [rGO] o /[Co 3 O 4 ] o /[Py] o  = 1:5:1; 1:5:2; 1:5:5 and 1:5:10 for 2 M and 6 M KOH solutions. The highest specific capacitances, energy and power densities of C sp  = 896 F × g −1 , E  = 31.75 Wh × kg −1 and P  = 11,705 W × kg −1 for [rGO] o /[Co 3 O 4 ] o /[Py] o  = 1:5:10 in 2 M KOH solution and C sp  = 1370 F × g −1 for [rGO] o /[Co 3 O 4 ] o /[Py] o  = 1:5:5 and E  = 31.43 Wh × kg −1 and P  = 11,600 W × kg −1 for [rGO] o /[Co 3 O 4 ] o /[Py] o  = 1:5:1 in 6 M KOH solution. The lowest capacitance retention was obtained as 3.69% in 2 M KOH solution for [rGO] o /[Co 3 O 4 ] o /[Py] o  = 1:5:1 after 1000 cycle charge/discharge performances by CV method. Symmetric supercapacitor of rGO/Co 3 O 4 /PPy should open up new opportunities for the next-generation high-performance supercapacitors.
doi_str_mv 10.1007/s11581-022-04764-4
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subjects Chemistry
Chemistry and Materials Science
Cobalt oxides
Condensed Matter Physics
Differential thermal analysis
Electrochemistry
Energy Storage
Graphene
Metal oxides
Nanocomposites
Optical and Electronic Materials
Original Paper
Polypyrroles
Renewable and Green Energy
Supercapacitors
title Symmetric supercapacitor device applications of rGO / Co3O4 / polypyrrole nanocomposites
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