Perspective on structure-property relationship of room temperature single-component liquid crystals

• Published in: Liquid crystals 2022-09, Vol.49 (12), p.1545-1603
• Main Authors: Shanker, Govindaswamy, Kumar, K. R. Sunil, Paul, Bishwajit
• Format: Article
• Language: English
• Subjects: Aldehydes; Benzenoids; Birefringence; Cameras; Composite materials; Crystals; device applications; Digital cameras; fragment-Based drug discovery; Functional groups; Halogens; Ketones; Liquid crystals; Molecular chains; molecular design; Molecular structure; Polarity; Room temperature; Room temperature liquid crystals; single-component; thermotropic
• ISSN: 0267-8292; 1366-5855
• DOI: 10.1080/02678292.2022.2102683

Ever since the serendipitous discovery of liquid crystals (LC) by Friedrich Reinitzer in 1888, a significant number of LCs have been synthesised and characterised. The ever-growing LCs emanating from conventional and non-conventional systems find applications in various electronic appliances such as flat-panel TV displays, notebooks, digital cameras, and domestic devices. The room temperature LCs (RT-LCs 20 to ±80 °C), either as single-component/composites, act as a starting point for such applications. Therefore, the quest for such RT-LCs is always valued and carved out as a promising niche for many such devices. Molecular design and the structure-property relationship are the recurrent themes for stable and single-component RT-LCs. The LC molecules starting from simple benzenoids to macrocycles with flexible hydrocarbon chains as spacer/terminal tails needed to be tethered in a precise pattern may lead to potential LCs. To craft stable and single-component RT-LCs, functional groups (nitrile, halogens, nitro, aldehydes, amine, thiol, alcohol, ketone, ester, amide) are frequently employed. RT-LCs with viscosity, dielectric, birefringence, and polarity enables the reduction of the number of components in a composites mixture. This review describes the genesis and importance of the single component RT-LCs, state-of-the-art LC research, perspectives, and new design strategies for venturing into a new horizon. * Elucidation of the design principles for molecular structure-based liquid crystals (LCs) and compiled the existing single component thermotropic (SLCs) based on the overview from literature. * Room temperature thermotropic LCs (RT-LCs 20 to ±80 °C) offer promising means to variety of device applications including flat panel TV displays, notebook, digital cameras, domestic devices. * Underlying principles for compounds featuring SLCs and insights from existing LCs can help in designing better SLCs that are yet to discovered by broadening the chemical space.