Loading…
Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract
Current work describes green synthesis of Fe, Mn (monometallic) and Fe-Mn (bimetallic) nanoparticles using Cannabis sativa leaf extract as stabilizing and capping agent. In order to assess the formation of nanoparticles UV/Vis and FTIR analysis was carried out. In addition, Scanning electron microsc...
Saved in:
| Published in: | Water (Basel) 2022-11, Vol.14 (21), p.3535 |
|---|---|
| Main Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353 |
| container_end_page | |
| container_issue | 21 |
| container_start_page | 3535 |
| container_title | Water (Basel) |
| container_volume | 14 |
| creator | Naz, Sadaf Kalsoom, Rimsha Ali, Faisal Amjed, Nyla Younas, Umer Pervaiz, Muhammad Alsaiari, Mabkhoot Faisal, M Harraz, Farid A Luque, Rafael |
| description | Current work describes green synthesis of Fe, Mn (monometallic) and Fe-Mn (bimetallic) nanoparticles using Cannabis sativa leaf extract as stabilizing and capping agent. In order to assess the formation of nanoparticles UV/Vis and FTIR analysis was carried out. In addition, Scanning electron microscopy and XRD studies confirmed synthesis as well as morphology of the nanoparticles. All the nanoparticles were found having particle size 20–80 nm and crystallite 3–20 nm. Photocatalytic activity of synthesized nanoparticles has been evaluated by carrying out degradation of two dyes methyl orange (MO) and Congo red (CR) in the presence of nanocatalysts. Degradation of both the dyes was carried out separately using Fe, Mn and Fe-Mn nanoparticles to compare the efficiency of monometallic with bimetallic nanoparticles. Iron and manganese monometallic particles have completely degraded MO in 18 min and 20 min and CR in 24 min and 18 min respectively. However, due to increased synergistic effect Fe-Mn BNPs completely degraded MO dye in just 12 min and CR in 14 min. In nutshell, this work is actually a step towards the synthesis of bimetallic nanoparticles using a plant extract with improved synergistic photocatalytic activities which impart various properties to the designed nanomaterial. |
| doi_str_mv | 10.3390/w14213535 |
| format | article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2734752535</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A810515009</galeid><sourcerecordid>A810515009</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353</originalsourceid><addsrcrecordid>eNptUUtLAzEQXkRBUQ_-g4Anwa3JJtndHku1KtQHas_LNI8a2U1qklbXq3_ciCIKzhzmY_i-eWbZAcEDSof45IWwglBO-Ua2U-CK5owxsvkLb2f7ITzhZGxY1xzvZO-3jy46ARHaPhqB7lTn1tAip9FprwLS3nVo9LxSbhXQlZJm1aF5jybqGF1ZBFYmmCd0DdYtwacSbVLd9zY-qmDelESzYOwCjcFamJuAAkSzBjRVoNHZa_Qg4l62paENav877mazydnD-CKf3pxfjkfTXFA-jHklRFXJCogWDBMla4FFoWkpeVlgAiXWRUWLQrE67VexeS0Fg5LPS0pqKdNZdrPDr7pL79JGITZPbuVtatkkJat4wX-zFtCqxljtPofsTBDNqCaYE47xMLEG_7CSS9UZ4azSJuX_CI6-BMK7ELzSzdKbDnzfENx8fq_5-R79AMgSid8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2734752535</pqid></control><display><type>article</type><title>Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract</title><source>Publicly Available Content Database (Proquest) (PQ_SDU_P3)</source><creator>Naz, Sadaf ; Kalsoom, Rimsha ; Ali, Faisal ; Amjed, Nyla ; Younas, Umer ; Pervaiz, Muhammad ; Alsaiari, Mabkhoot ; Faisal, M ; Harraz, Farid A ; Luque, Rafael</creator><creatorcontrib>Naz, Sadaf ; Kalsoom, Rimsha ; Ali, Faisal ; Amjed, Nyla ; Younas, Umer ; Pervaiz, Muhammad ; Alsaiari, Mabkhoot ; Faisal, M ; Harraz, Farid A ; Luque, Rafael</creatorcontrib><description>Current work describes green synthesis of Fe, Mn (monometallic) and Fe-Mn (bimetallic) nanoparticles using Cannabis sativa leaf extract as stabilizing and capping agent. In order to assess the formation of nanoparticles UV/Vis and FTIR analysis was carried out. In addition, Scanning electron microscopy and XRD studies confirmed synthesis as well as morphology of the nanoparticles. All the nanoparticles were found having particle size 20–80 nm and crystallite 3–20 nm. Photocatalytic activity of synthesized nanoparticles has been evaluated by carrying out degradation of two dyes methyl orange (MO) and Congo red (CR) in the presence of nanocatalysts. Degradation of both the dyes was carried out separately using Fe, Mn and Fe-Mn nanoparticles to compare the efficiency of monometallic with bimetallic nanoparticles. Iron and manganese monometallic particles have completely degraded MO in 18 min and 20 min and CR in 24 min and 18 min respectively. However, due to increased synergistic effect Fe-Mn BNPs completely degraded MO dye in just 12 min and CR in 14 min. In nutshell, this work is actually a step towards the synthesis of bimetallic nanoparticles using a plant extract with improved synergistic photocatalytic activities which impart various properties to the designed nanomaterial.</description><identifier>ISSN: 2073-4441</identifier><identifier>EISSN: 2073-4441</identifier><identifier>DOI: 10.3390/w14213535</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Aqueous solutions ; Bimetals ; Cannabis ; Cannabis sativa ; Catalytic activity ; Caustic soda ; Chemical properties ; Chloride ; Color removal ; Comparative analysis ; Control ; Crystallites ; Crystals ; Dyes ; Dyes and dyeing ; Environmental aspects ; Iron ; Leaves ; Manganese ; Marijuana ; Materia medica, Vegetable ; Metals ; Nanomaterials ; Nanoparticles ; Photocatalysis ; Phytochemicals ; Plant extracts ; Pollutants ; Purification ; Radiation ; Salt ; Scanning electron microscopy ; Sewage ; Synergistic effect</subject><ispartof>Water (Basel), 2022-11, Vol.14 (21), p.3535</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353</citedby><cites>FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353</cites><orcidid>0000-0003-4190-1916 ; 0000-0002-4366-3256 ; 0000-0002-9054-1710 ; 0000-0001-6889-327X ; 0000-0001-7776-7099</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2734752535/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2734752535?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,25731,27901,27902,36989,44566,74869</link.rule.ids></links><search><creatorcontrib>Naz, Sadaf</creatorcontrib><creatorcontrib>Kalsoom, Rimsha</creatorcontrib><creatorcontrib>Ali, Faisal</creatorcontrib><creatorcontrib>Amjed, Nyla</creatorcontrib><creatorcontrib>Younas, Umer</creatorcontrib><creatorcontrib>Pervaiz, Muhammad</creatorcontrib><creatorcontrib>Alsaiari, Mabkhoot</creatorcontrib><creatorcontrib>Faisal, M</creatorcontrib><creatorcontrib>Harraz, Farid A</creatorcontrib><creatorcontrib>Luque, Rafael</creatorcontrib><title>Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract</title><title>Water (Basel)</title><description>Current work describes green synthesis of Fe, Mn (monometallic) and Fe-Mn (bimetallic) nanoparticles using Cannabis sativa leaf extract as stabilizing and capping agent. In order to assess the formation of nanoparticles UV/Vis and FTIR analysis was carried out. In addition, Scanning electron microscopy and XRD studies confirmed synthesis as well as morphology of the nanoparticles. All the nanoparticles were found having particle size 20–80 nm and crystallite 3–20 nm. Photocatalytic activity of synthesized nanoparticles has been evaluated by carrying out degradation of two dyes methyl orange (MO) and Congo red (CR) in the presence of nanocatalysts. Degradation of both the dyes was carried out separately using Fe, Mn and Fe-Mn nanoparticles to compare the efficiency of monometallic with bimetallic nanoparticles. Iron and manganese monometallic particles have completely degraded MO in 18 min and 20 min and CR in 24 min and 18 min respectively. However, due to increased synergistic effect Fe-Mn BNPs completely degraded MO dye in just 12 min and CR in 14 min. In nutshell, this work is actually a step towards the synthesis of bimetallic nanoparticles using a plant extract with improved synergistic photocatalytic activities which impart various properties to the designed nanomaterial.</description><subject>Aqueous solutions</subject><subject>Bimetals</subject><subject>Cannabis</subject><subject>Cannabis sativa</subject><subject>Catalytic activity</subject><subject>Caustic soda</subject><subject>Chemical properties</subject><subject>Chloride</subject><subject>Color removal</subject><subject>Comparative analysis</subject><subject>Control</subject><subject>Crystallites</subject><subject>Crystals</subject><subject>Dyes</subject><subject>Dyes and dyeing</subject><subject>Environmental aspects</subject><subject>Iron</subject><subject>Leaves</subject><subject>Manganese</subject><subject>Marijuana</subject><subject>Materia medica, Vegetable</subject><subject>Metals</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Photocatalysis</subject><subject>Phytochemicals</subject><subject>Plant extracts</subject><subject>Pollutants</subject><subject>Purification</subject><subject>Radiation</subject><subject>Salt</subject><subject>Scanning electron microscopy</subject><subject>Sewage</subject><subject>Synergistic effect</subject><issn>2073-4441</issn><issn>2073-4441</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNptUUtLAzEQXkRBUQ_-g4Anwa3JJtndHku1KtQHas_LNI8a2U1qklbXq3_ciCIKzhzmY_i-eWbZAcEDSof45IWwglBO-Ua2U-CK5owxsvkLb2f7ITzhZGxY1xzvZO-3jy46ARHaPhqB7lTn1tAip9FprwLS3nVo9LxSbhXQlZJm1aF5jybqGF1ZBFYmmCd0DdYtwacSbVLd9zY-qmDelESzYOwCjcFamJuAAkSzBjRVoNHZa_Qg4l62paENav877mazydnD-CKf3pxfjkfTXFA-jHklRFXJCogWDBMla4FFoWkpeVlgAiXWRUWLQrE67VexeS0Fg5LPS0pqKdNZdrPDr7pL79JGITZPbuVtatkkJat4wX-zFtCqxljtPofsTBDNqCaYE47xMLEG_7CSS9UZ4azSJuX_CI6-BMK7ELzSzdKbDnzfENx8fq_5-R79AMgSid8</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Naz, Sadaf</creator><creator>Kalsoom, Rimsha</creator><creator>Ali, Faisal</creator><creator>Amjed, Nyla</creator><creator>Younas, Umer</creator><creator>Pervaiz, Muhammad</creator><creator>Alsaiari, Mabkhoot</creator><creator>Faisal, M</creator><creator>Harraz, Farid A</creator><creator>Luque, Rafael</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-4190-1916</orcidid><orcidid>https://orcid.org/0000-0002-4366-3256</orcidid><orcidid>https://orcid.org/0000-0002-9054-1710</orcidid><orcidid>https://orcid.org/0000-0001-6889-327X</orcidid><orcidid>https://orcid.org/0000-0001-7776-7099</orcidid></search><sort><creationdate>20221101</creationdate><title>Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract</title><author>Naz, Sadaf ; Kalsoom, Rimsha ; Ali, Faisal ; Amjed, Nyla ; Younas, Umer ; Pervaiz, Muhammad ; Alsaiari, Mabkhoot ; Faisal, M ; Harraz, Farid A ; Luque, Rafael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Bimetals</topic><topic>Cannabis</topic><topic>Cannabis sativa</topic><topic>Catalytic activity</topic><topic>Caustic soda</topic><topic>Chemical properties</topic><topic>Chloride</topic><topic>Color removal</topic><topic>Comparative analysis</topic><topic>Control</topic><topic>Crystallites</topic><topic>Crystals</topic><topic>Dyes</topic><topic>Dyes and dyeing</topic><topic>Environmental aspects</topic><topic>Iron</topic><topic>Leaves</topic><topic>Manganese</topic><topic>Marijuana</topic><topic>Materia medica, Vegetable</topic><topic>Metals</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Photocatalysis</topic><topic>Phytochemicals</topic><topic>Plant extracts</topic><topic>Pollutants</topic><topic>Purification</topic><topic>Radiation</topic><topic>Salt</topic><topic>Scanning electron microscopy</topic><topic>Sewage</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Naz, Sadaf</creatorcontrib><creatorcontrib>Kalsoom, Rimsha</creatorcontrib><creatorcontrib>Ali, Faisal</creatorcontrib><creatorcontrib>Amjed, Nyla</creatorcontrib><creatorcontrib>Younas, Umer</creatorcontrib><creatorcontrib>Pervaiz, Muhammad</creatorcontrib><creatorcontrib>Alsaiari, Mabkhoot</creatorcontrib><creatorcontrib>Faisal, M</creatorcontrib><creatorcontrib>Harraz, Farid A</creatorcontrib><creatorcontrib>Luque, Rafael</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Publicly Available Content Database (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Water (Basel)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Naz, Sadaf</au><au>Kalsoom, Rimsha</au><au>Ali, Faisal</au><au>Amjed, Nyla</au><au>Younas, Umer</au><au>Pervaiz, Muhammad</au><au>Alsaiari, Mabkhoot</au><au>Faisal, M</au><au>Harraz, Farid A</au><au>Luque, Rafael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract</atitle><jtitle>Water (Basel)</jtitle><date>2022-11-01</date><risdate>2022</risdate><volume>14</volume><issue>21</issue><spage>3535</spage><pages>3535-</pages><issn>2073-4441</issn><eissn>2073-4441</eissn><abstract>Current work describes green synthesis of Fe, Mn (monometallic) and Fe-Mn (bimetallic) nanoparticles using Cannabis sativa leaf extract as stabilizing and capping agent. In order to assess the formation of nanoparticles UV/Vis and FTIR analysis was carried out. In addition, Scanning electron microscopy and XRD studies confirmed synthesis as well as morphology of the nanoparticles. All the nanoparticles were found having particle size 20–80 nm and crystallite 3–20 nm. Photocatalytic activity of synthesized nanoparticles has been evaluated by carrying out degradation of two dyes methyl orange (MO) and Congo red (CR) in the presence of nanocatalysts. Degradation of both the dyes was carried out separately using Fe, Mn and Fe-Mn nanoparticles to compare the efficiency of monometallic with bimetallic nanoparticles. Iron and manganese monometallic particles have completely degraded MO in 18 min and 20 min and CR in 24 min and 18 min respectively. However, due to increased synergistic effect Fe-Mn BNPs completely degraded MO dye in just 12 min and CR in 14 min. In nutshell, this work is actually a step towards the synthesis of bimetallic nanoparticles using a plant extract with improved synergistic photocatalytic activities which impart various properties to the designed nanomaterial.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/w14213535</doi><orcidid>https://orcid.org/0000-0003-4190-1916</orcidid><orcidid>https://orcid.org/0000-0002-4366-3256</orcidid><orcidid>https://orcid.org/0000-0002-9054-1710</orcidid><orcidid>https://orcid.org/0000-0001-6889-327X</orcidid><orcidid>https://orcid.org/0000-0001-7776-7099</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2073-4441 |
| ispartof | Water (Basel), 2022-11, Vol.14 (21), p.3535 |
| issn | 2073-4441 2073-4441 |
| language | eng |
| recordid | cdi_proquest_journals_2734752535 |
| source | Publicly Available Content Database (Proquest) (PQ_SDU_P3) |
| subjects | Aqueous solutions Bimetals Cannabis Cannabis sativa Catalytic activity Caustic soda Chemical properties Chloride Color removal Comparative analysis Control Crystallites Crystals Dyes Dyes and dyeing Environmental aspects Iron Leaves Manganese Marijuana Materia medica, Vegetable Metals Nanomaterials Nanoparticles Photocatalysis Phytochemicals Plant extracts Pollutants Purification Radiation Salt Scanning electron microscopy Sewage Synergistic effect |
| title | Photocatalytic Removal of Dyes from Aqueous Medium by Fe, Mn and Fe-Mn Nanoparticles Synthesized Using Cannabis sativa Leaf Extract |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T06%3A42%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photocatalytic%20Removal%20of%20Dyes%20from%20Aqueous%20Medium%20by%20Fe,%20Mn%20and%20Fe-Mn%20Nanoparticles%20Synthesized%20Using%20Cannabis%20sativa%20Leaf%20Extract&rft.jtitle=Water%20(Basel)&rft.au=Naz,%20Sadaf&rft.date=2022-11-01&rft.volume=14&rft.issue=21&rft.spage=3535&rft.pages=3535-&rft.issn=2073-4441&rft.eissn=2073-4441&rft_id=info:doi/10.3390/w14213535&rft_dat=%3Cgale_proqu%3EA810515009%3C/gale_proqu%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c359t-7cc77d7a1fc401ed8c0c2f36d56201a60f27322e4800074b8dc4a65b6318dd353%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2734752535&rft_id=info:pmid/&rft_galeid=A810515009&rfr_iscdi=true |