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Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium() complex
A new promising method for the preparation of crystalline 2D polymers based on tetra(4-pyridyl)porphyrin has been developed. Radical anion {H 2 T(4-Py)P&z.rad; − } species are used as the starting material. A new solid-state supramolecular array [{H 2 T(4-Py)P}·{Tb III (TMHD) 3 } 2 ]·2.84C 6 H 1...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2022-11, Vol.51 (44), p.16921-16925 |
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| Main Authors: | , , , , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c380t-6ff0652c9500582eec97fa1c43939e8f109d2f5af44c2cde989031af7958b0fb3 |
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| cites | cdi_FETCH-LOGICAL-c380t-6ff0652c9500582eec97fa1c43939e8f109d2f5af44c2cde989031af7958b0fb3 |
| container_end_page | 16925 |
| container_issue | 44 |
| container_start_page | 16921 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Nazarov, Dmitry I Faraonov, Maxim A Kuzmin, Alexey V Khasanov, Salavat S Otsuka, Akihiro Yamochi, Hideki Kitagawa, Hiroshi Konarev, Dmitri V |
| description | A new promising method for the preparation of crystalline 2D polymers based on tetra(4-pyridyl)porphyrin has been developed. Radical anion {H
2
T(4-Py)P&z.rad;
−
} species are used as the starting material. A new solid-state supramolecular array [{H
2
T(4-Py)P}·{Tb
III
(TMHD)
3
}
2
]·2.84C
6
H
14
(
1
) in which porphyrin units are bridged with Tb
III
ions to form a self-assembled 2D polymer has been obtained. The complex contains neutral porphyrin macrocycles, which is supported by optical and magnetic data. High-spin paramagnetic Tb
III
ions are weakly antiferromagnetically coupled in accordance with rather long distances between them.
A new crystalline hybrid organic-inorganic two-dimensional supramolecular polymer of the tetra(4-pyridyl)porphyrin and terbium(
iii
) complex, Tb
III
(TMHD)
3
, has been obtained and investigated. |
| doi_str_mv | 10.1039/d2dt03170a |
| format | article |
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2
T(4-Py)P&z.rad;
−
} species are used as the starting material. A new solid-state supramolecular array [{H
2
T(4-Py)P}·{Tb
III
(TMHD)
3
}
2
]·2.84C
6
H
14
(
1
) in which porphyrin units are bridged with Tb
III
ions to form a self-assembled 2D polymer has been obtained. The complex contains neutral porphyrin macrocycles, which is supported by optical and magnetic data. High-spin paramagnetic Tb
III
ions are weakly antiferromagnetically coupled in accordance with rather long distances between them.
A new crystalline hybrid organic-inorganic two-dimensional supramolecular polymer of the tetra(4-pyridyl)porphyrin and terbium(
iii
) complex, Tb
III
(TMHD)
3
, has been obtained and investigated.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt03170a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Antiferromagnetism ; Polymers ; Porphyrins ; Self-assembly</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-11, Vol.51 (44), p.16921-16925</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-6ff0652c9500582eec97fa1c43939e8f109d2f5af44c2cde989031af7958b0fb3</citedby><cites>FETCH-LOGICAL-c380t-6ff0652c9500582eec97fa1c43939e8f109d2f5af44c2cde989031af7958b0fb3</cites><orcidid>0000-0002-7326-8118 ; 0000-0003-0805-601X ; 0000-0002-0127-6530 ; 0000-0002-3141-0702 ; 0000-0001-6955-3015</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Nazarov, Dmitry I</creatorcontrib><creatorcontrib>Faraonov, Maxim A</creatorcontrib><creatorcontrib>Kuzmin, Alexey V</creatorcontrib><creatorcontrib>Khasanov, Salavat S</creatorcontrib><creatorcontrib>Otsuka, Akihiro</creatorcontrib><creatorcontrib>Yamochi, Hideki</creatorcontrib><creatorcontrib>Kitagawa, Hiroshi</creatorcontrib><creatorcontrib>Konarev, Dmitri V</creatorcontrib><title>Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium() complex</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A new promising method for the preparation of crystalline 2D polymers based on tetra(4-pyridyl)porphyrin has been developed. Radical anion {H
2
T(4-Py)P&z.rad;
−
} species are used as the starting material. A new solid-state supramolecular array [{H
2
T(4-Py)P}·{Tb
III
(TMHD)
3
}
2
]·2.84C
6
H
14
(
1
) in which porphyrin units are bridged with Tb
III
ions to form a self-assembled 2D polymer has been obtained. The complex contains neutral porphyrin macrocycles, which is supported by optical and magnetic data. High-spin paramagnetic Tb
III
ions are weakly antiferromagnetically coupled in accordance with rather long distances between them.
A new crystalline hybrid organic-inorganic two-dimensional supramolecular polymer of the tetra(4-pyridyl)porphyrin and terbium(
iii
) complex, Tb
III
(TMHD)
3
, has been obtained and investigated.</description><subject>Antiferromagnetism</subject><subject>Polymers</subject><subject>Porphyrins</subject><subject>Self-assembly</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkctLAzEQxoMoWKsX78KClyqs5rGvHEvrCwQv9byk2Yndkt3EJAvuf29qpYKn-Yb5zTDzDUKXBN8RzPh9Q5uAGSmxOEITkpVlyinLjg-aFqfozPstxpTinE5Qu3CjD0LrtofECic68dFDaGXiBxszo0EOWriELlNr9NiBS4xKwgaSAMGJWZba0bXNqG-scXYTdZ-IvolVt26HbnaTSNNZDV_n6EQJ7eHiN07R--PDavGcvr49vSzmr6lkFQ5poRQucip5jnFeUQDJSyWIzBhnHCpFMG-oyoXKMkllA7zi8WChSp5Xa6zWbIpm-7nWmc8BfKi71kvQWvRgBl_TksUGXhIW0et_6NYMro_b7aiCsAIXNFK3e0o6470DVVvXdsKNNcH1zvV6SZerH9fnEb7aw87LA_f3FfYNT8R_JA</recordid><startdate>20221115</startdate><enddate>20221115</enddate><creator>Nazarov, Dmitry I</creator><creator>Faraonov, Maxim A</creator><creator>Kuzmin, Alexey V</creator><creator>Khasanov, Salavat S</creator><creator>Otsuka, Akihiro</creator><creator>Yamochi, Hideki</creator><creator>Kitagawa, Hiroshi</creator><creator>Konarev, Dmitri V</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7326-8118</orcidid><orcidid>https://orcid.org/0000-0003-0805-601X</orcidid><orcidid>https://orcid.org/0000-0002-0127-6530</orcidid><orcidid>https://orcid.org/0000-0002-3141-0702</orcidid><orcidid>https://orcid.org/0000-0001-6955-3015</orcidid></search><sort><creationdate>20221115</creationdate><title>Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium() complex</title><author>Nazarov, Dmitry I ; Faraonov, Maxim A ; Kuzmin, Alexey V ; Khasanov, Salavat S ; Otsuka, Akihiro ; Yamochi, Hideki ; Kitagawa, Hiroshi ; Konarev, Dmitri V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-6ff0652c9500582eec97fa1c43939e8f109d2f5af44c2cde989031af7958b0fb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Antiferromagnetism</topic><topic>Polymers</topic><topic>Porphyrins</topic><topic>Self-assembly</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nazarov, Dmitry I</creatorcontrib><creatorcontrib>Faraonov, Maxim A</creatorcontrib><creatorcontrib>Kuzmin, Alexey V</creatorcontrib><creatorcontrib>Khasanov, Salavat S</creatorcontrib><creatorcontrib>Otsuka, Akihiro</creatorcontrib><creatorcontrib>Yamochi, Hideki</creatorcontrib><creatorcontrib>Kitagawa, Hiroshi</creatorcontrib><creatorcontrib>Konarev, Dmitri V</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nazarov, Dmitry I</au><au>Faraonov, Maxim A</au><au>Kuzmin, Alexey V</au><au>Khasanov, Salavat S</au><au>Otsuka, Akihiro</au><au>Yamochi, Hideki</au><au>Kitagawa, Hiroshi</au><au>Konarev, Dmitri V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium() complex</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2022-11-15</date><risdate>2022</risdate><volume>51</volume><issue>44</issue><spage>16921</spage><epage>16925</epage><pages>16921-16925</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new promising method for the preparation of crystalline 2D polymers based on tetra(4-pyridyl)porphyrin has been developed. Radical anion {H
2
T(4-Py)P&z.rad;
−
} species are used as the starting material. A new solid-state supramolecular array [{H
2
T(4-Py)P}·{Tb
III
(TMHD)
3
}
2
]·2.84C
6
H
14
(
1
) in which porphyrin units are bridged with Tb
III
ions to form a self-assembled 2D polymer has been obtained. The complex contains neutral porphyrin macrocycles, which is supported by optical and magnetic data. High-spin paramagnetic Tb
III
ions are weakly antiferromagnetically coupled in accordance with rather long distances between them.
A new crystalline hybrid organic-inorganic two-dimensional supramolecular polymer of the tetra(4-pyridyl)porphyrin and terbium(
iii
) complex, Tb
III
(TMHD)
3
, has been obtained and investigated.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2dt03170a</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7326-8118</orcidid><orcidid>https://orcid.org/0000-0003-0805-601X</orcidid><orcidid>https://orcid.org/0000-0002-0127-6530</orcidid><orcidid>https://orcid.org/0000-0002-3141-0702</orcidid><orcidid>https://orcid.org/0000-0001-6955-3015</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-11, Vol.51 (44), p.16921-16925 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2736136062 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Antiferromagnetism Polymers Porphyrins Self-assembly |
| title | Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium() complex |
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