Trends in the sulfuric acid-catalyzed consumption of styrene epoxide in an alcohol medium

The kinetics of consumption of styrene epoxide (2) and accumulation of benzaldehyde (3) catalyzed by sulfuric acid (1) in an alcohol medium was studied in a bubbling glass reactor in an oxygen atmosphere. The dependences of the rates of consumption of 2 and accumulation of 3 on the concentrations of...

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Bibliographic Details
Published in:Russian chemical bulletin 2022-10, Vol.71 (10), p.2138-2141
Main Authors: Petrov, L. V., Solyanikov, V. M.
Format: Article
Language:English
Subjects:
Accumulation
Benzaldehyde
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Consumption
Full Articles
Inorganic Chemistry
Organic Chemistry
Styrenes
Sulfuric acid
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Summary:The kinetics of consumption of styrene epoxide (2) and accumulation of benzaldehyde (3) catalyzed by sulfuric acid (1) in an alcohol medium was studied in a bubbling glass reactor in an oxygen atmosphere. The dependences of the rates of consumption of 2 and accumulation of 3 on the concentrations of reactants 1 and 2 are of the same type: V 2 = k 2 [ 1 ] 1 [ 2 ] 0 , V 3 = k 3 [ 1 ] 1 [ 2 ] 0 . Data indicating an important role of the anions of acid catalysts in the conversions of epoxides were obtained.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3638-4