Understanding the role of ZnO as activator in SBR vulcanizates: Performance evaluation with active, nano, and functionalized ZnO

• Published in: Journal of applied polymer science 2023-01, Vol.140 (1), p.n/a
• Main Authors: Sreethu, Thiyyanthiruthy Kumbalaparambil, Das, Mithun, Parathodika, Arshad Rahman, Bhattacharya, Asit Baran, Naskar, Kinsuk
• Format: Article
• Language: English
• Subjects: crosslink density; Curing; dispersion; Elongation; Freezing; Materials science; Mechanical properties; Melting points; Performance evaluation; Polymers; Reaction kinetics; Rubber; styrene butadiene rubber; Tensile strength; Vulcanization; Zinc oxide
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.53257

This study investigates (ZnO)s with different surface features as vulcanization activators in unfilled SBR vulcanizates. ZnO is termed the best activator due to its fast reaction kinetics. A high release of ZnO into the environment harms marine ecosystems, and most ZnO production goes to the rubber sector; therefore, reducing ZnO amount is essential. Active, nano and functionalized ZnO compared to conventional ZnO in SBR matrix; concentration optimized based on curing, mechanical, physical, and dispersion analyses. The Arrhenius equation approximated the cure curve's kinetic constant and activation energy. Crosslink density measured by swelling experiment and solvent freezing point depression. Nano ZnO was used from 0.5 to 2phr, active ZnO from 1 to 4phr, and functionalized ZnO from 1 to 3phr compared to 5phr of conventional ZnO. The tensile strength of N1.5, F1.5, and A2 SBR increased by 5%, 26%, and 18% compared to C5SBR, whose elongation at break improved by 30%, 7%, and 23%. The data were analyzed using tukey HSD post hoc test. Regarding mechanical properties and curing characteristics, 2phr active, functionalized, and 1.5phr nano ZnO is analogous to 5phr conventional ZnO in an unfilled SBR matrix. The quantity of ZnO in rubber vulcanizates decreased successively by 60%, 60%, and 70%.