Microstructure control and strengthening mechanism of fine-grained cast Mg alloys based on grain boundary segregation of Al solute

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2022-08, Vol.851, p.143665, Article 143665
• Main Authors: Lin, Xiaoping, Dang, Yuzhen, Dai, Penglin, Fang, Daran, Xu, Chang, Wen, Bin
• Format: Article
• Language: English
• Subjects: Alloys; Aluminum; Bonding strength; Boundaries; Compressive properties; Compressive strength; Concentration gradient; Electron backscatter diffraction; First principles; Grain boundaries; Grain Boundary Segregation; High pressure; High pressure solidification; Magnesium base alloys; Mg–Al alloy; Microstructure; Solid solution; Solid solutions; Solidification; Strengthening
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/j.msea.2022.143665

Mg-xAl alloys (x = 3–12 wt%) were prepared by high pressure solidification. The microstructure of the alloys was studied using Scanning Electron Microscope (SEM) and Electron Backscatter Diffraction (EBSD), and the strengthening mechanism was analyzed in combination with the compressive properties of the experimental alloys. Furthermore, the grain boundary segregation of Al solute was investigated by experiments and first-principles calculations. For the Mg-xAl alloys solidified under atmospheric pressure, the microstructure will be a single solid solution when the Al content of the alloy is less than 5 wt%. However, for the Mg-xAl alloys solidified under 4 GPa pressure, the microstructure will always ba e single solid solution when the Al content of the alloy is less than 12 wt%. Moreover, the segregation of Al solute with a high concentration gradient can be observed at plenty of grain boundaries (area fraction is as high as 46%), because α-Mg dendrites are significantly refined under high pressure. In addition, many Al atoms are dissolved in the α-Mg matrix owing to high pressure. On this basis, it is found that grain boundary segregation of Al solute can decrease the grain boundary energy, and increase the bonding strength of grain boundaries. As a result, the Mg–Al alloys solidified under high pressure have superior compression properties. The compression strength of the Mg–9%Al alloy and the Mg–12%Al alloy solidified under 4 GPa is as high as 458 MPa and 490 MPa respectively, the alloys retain superior plasticity simultaneously.