Brij 58–activated carbon assisted synthesis of Ag/Ag2O/TiO2-AC photocatalysts for efficient organic pollutants degradation

• Published in: Journal of alloys and compounds 2023-01, Vol.931, p.167528, Article 167528
• Main Authors: Negoescu, Daniela, Atkinson, Irina, Gherendi, Mihaela, Culita, Daniela C., Baran, Adriana, Petrescu, Simona, Trica, Bogdan, Pelinescu, Diana, Ionescu, Robertina, Bratan, Veronica, Parvulescu, Viorica
• Format: Article
• Language: English
• Subjects: Activated carbon; Adsorption; Ag/Ag2O/C/P-TiO2; Amorphization; Anatase; Antibiotics; Brilliant Blue FCF; Ciprofloxacin; Composite materials; Composites; Dyes; Optical properties; Organic chemistry; Phosphoric acid; Photocatalysis; Photocatalysts; Photocatalytic degradation; Photodegradation; Photoelectrons; Photoluminescence; Pollutants; Precursors; Sol-gel processes; Spectrum analysis; Surface chemistry; Titanium; Titanium dioxide; Toxicity; Transmission electron microscopy; X ray photoelectron spectroscopy; X-ray diffraction
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2022.167528

TiO2-activated carbon composites with mesoporous structure were prepared by sol-gel method using different titanium precursors (titanium tetraisopropoxide, tetraethyl orthotitanate) and surfactants (Brij 58 and activated carbon). Two different activated carbons (AC and ACP), obtained from ground coffee, were activated in different conditions with orto-phosphoric acid. Finaly the obtained supports were dopped with Ag (1%). The crystalline structure, morphology, mesoporous structure, surface composition and optical properties of Ag/Ag2O/C/P/TiO2 photocatalysts were characterized by X-ray diffraction (XRD), BET surface area measurements, scanning and transmission electron microscopy (SEM, TEM), X-ray photoelectron spectroscopy (XPS), Raman, diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) techniques. A significant effect of activated carbon and titanium precursor on TiO2 crystalline phase was evidenced. Thus, XRD and TEM evidenced amorphization of TiO2 structure for samples with high phosphorus percent in activated carbon. As well, a small amount of rutile, together anatase, stood out for samples obtained from tetraethyl orthotitanate. XPS spectra revealed the presence of Ag1+, Ag0, C-C, C-O, C-P, and P-O species on the surface with significant effect on adsorption and photocatalytic degradation of Brilliant Blue FCF dye and antibiotic Ciprofloxacin. The best activity and no toxicity of the obtained water after Ciprofloxacin photodegradation was evidenced for the sample with higher P content. The obtained results highlighted that activated carbon play an outstanding role in the mechanism of dye and antibiotic photodegradation influencing both the adsorption of organic molecules and photocatalytic performances of p-n Ag2O/TiO2 heteroconjunction from composite materials. [Display omitted] •Mesoporous TiO2-activated carbon (AC) composites obtained by Brij 58-AC assisted sol-gel method.•Carbon samples, obtained from coffee grounds, were activated with orto-phosphoric acid.•The influence of AC with high P content on TiO2 structure, adsorption and photocatalytic reaction.•AC acts as an electron sink and Ag nanoparticles favor the capture of electrons.•Ag/Ag2O/TiO2-AC were used in degradation of Brilliant Blue dye and Ciprofloxacin antibiotic.