Benzotriazole corrosion inhibitor loaded nanocontainer based on g-C3N4 and hollow polyaniline spheres towards enhancing anticorrosion performance of waterborne epoxy coatings

• Published in: Progress in organic coatings 2023-01, Vol.174, p.107276, Article 107276
• Main Authors: Li, Changhua, Zhang, Chen, He, Yi, Li, Hongjie, Zhao, Yang, Li, Zhijun, Sun, Dan, Yin, Xiangying
• Format: Article
• Language: English
• Subjects: Anticorrosion; Barrier/self-healing dual properties; Barriers; Benzotriazole; Carbon nitride; Coating effects; Containers; Controlled release; Corrosion; Corrosion effects; Corrosion inhibitors; Corrosion prevention; Epoxy coatings; Epoxy resins; g-C3N4; Lamella; Marine environment; Multi-dimensional nanocontainer; PANI; Polyanilines; Self healing materials; Service life
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2022.107276

Multi-dimensional composite nanocontainers provided an opportunity to prolong the service life of waterborne self-healing coatings through combining intelligent protection with physical barrier. Herein, we constructed a benzotriazole (BTA) corrosion inhibitor loaded nanocontainer with barrier/controlled release/corrosion inhibition properties by assembling graphitic (g)-C3N4 lamella, hollow polyaniline capsule and outer polydopamine wall. Hollow polyaniline and g-C3N4 lamella with adsorption properties provide effective space and sites for loading BTA corrosion inhibitor. Outer polydopamine wall can not only realize the controlled release of corrosion inhibitor, but also ensure the good compatibility between the composite container and the water-based epoxy resin. In addition, polydopamine (PDA) and polyaniline (PANI) as a container frame can also serve as active inhibitors after the release of corrosion inhibitor to enhance the self-healing protection effect of waterborne coatings. In comparative evaluation, the composite coatings containing BTA-loaded nanocontainers (0.5 wt.%) exhibit obviously physical barrier effect after soaking in 3.5 wt.% NaCl solution for 40 days, and maintains good protective performance after immersion for 80 days. Meanwhile, the artificial scratch experiment verified the effective self-repair protection of the composite container to the coating under the condition of damage. To be sure, it will provide an effective improvement idea for the long-term application of waterborne epoxy coating in marine environment. Herein, we constructed a nearly three-dimensional functional container with barrier/self-healing dual properties by simple assembling of g-C3N4 lamella, hollow polyaniline capsule and outer polydopamine wall. Hollow polyaniline and g-C3N4 lamella with adsorption properties provide effective space and sites for loading BTA corrosion inhibitor. Outer polydopamine wall can not only realize the controlled release of corrosion inhibitor, but also ensure the good compatibility between the composite container and the water-based epoxy resin. In addition, PDA and PANI as a container frame can also serve as active inhibitors after the release of corrosion inhibitor, further enhancing the self-healing protection effect of waterborne coatings. [Display omitted] •Hollow polyaniline provides effective space for loading BTA corrosion inhibitor.•Outer polydopamine wall realizes the controlled release of BTA corrosion inhibitor.•Polydopa