Loading…

Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production

The efficient application of solar energy to realize photocatalytic biomass conversion to value-added chemicals is of significance. Herein, we propose a novel metal-free photocatalyst (4CzIPN@CMC-HG), which was prepared by encapsulating 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene (4CzIPN) in...

Full description

Saved in:
Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2023-01, Vol.25 (2), p.736-745
Main Authors: Sun, Shaofei, Sun, Shaochao, Liu, Kangning, Xiao, Ling-Ping, Ma, Jiliang, Sun, Runcang
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3
cites cdi_FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3
container_end_page 745
container_issue 2
container_start_page 736
container_title Green chemistry : an international journal and green chemistry resource : GC
container_volume 25
creator Sun, Shaofei
Sun, Shaochao
Liu, Kangning
Xiao, Ling-Ping
Ma, Jiliang
Sun, Runcang
description The efficient application of solar energy to realize photocatalytic biomass conversion to value-added chemicals is of significance. Herein, we propose a novel metal-free photocatalyst (4CzIPN@CMC-HG), which was prepared by encapsulating 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene (4CzIPN) in a carboxymethylcellulose-based hydrogel (CMC-HG) using a one-step thermal polymerization strategy. 4CzIPN@CMC-HG has an efficient photon-to-electron conversion rate, excellent visible light absorption, fast photogenerated carrier migration/separation, and high photocatalytic activity, with 90.7% yield of lactic acid (LA) and 100.0% conversion of xylose due to the synergistic effects between 4CzIPN and CMC-HG. 4CzIPN@CMC-HG showed remarkable universality and excellent stability, and the 1000-times amplification system indicated that this system has a potential industrial application in LA production. Furthermore, trapping experiments indicated that ˙OH, h + , 1 O 2 , and ˙O 2 − contributed to LA synthesis, with ˙O 2 − taking a leading role. These results showed the promising application prospects of metal-free photocatalysts in the photocatalytic biomass conversion to value-added chemicals.
doi_str_mv 10.1039/D2GC04336J
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2767745670</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2767745670</sourcerecordid><originalsourceid>FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3</originalsourceid><addsrcrecordid>eNpNkV9rFDEUxQepYLv64icI9MXKRpNJJtl5LKtdlYIv-jzcZG7c2aaTNcmI00_ox2qWtX_gwrkXDud34FbVW84-cCbaj5_qzZpJIdS3F9Upl0rQttbs5HFX9avqLKUdY5xrJU-rf-swphwnm4cwkuAIkFvM4KmLiGS_DTlYKPecMvkzAMHRwj5NHh78fFkvxbKhGXOEmyG9sxAN3AWPtKWzv6ByqWg_2BnGYHC8wxHJMBbMwRf-zoW2nb1F7ycfElIDCXuynfsYfqEnLsTnLfJgiQd7ELBDT_Yx9Mfur6uXDnzCN_91Uf28-vxj_YVef998XV9eU8tXbaaCKa20Ubopg_2q0RIdk227km1jwbTaGddovnJYoxFOqV5x00vhOAMwRiyq82NuQf-eMOVuF6Y4FmRXl2QtSzArrvdHl40hpYiu28fhFuLccdYdPtU9fUrcA677iiY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2767745670</pqid></control><display><type>article</type><title>Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Sun, Shaofei ; Sun, Shaochao ; Liu, Kangning ; Xiao, Ling-Ping ; Ma, Jiliang ; Sun, Runcang</creator><creatorcontrib>Sun, Shaofei ; Sun, Shaochao ; Liu, Kangning ; Xiao, Ling-Ping ; Ma, Jiliang ; Sun, Runcang</creatorcontrib><description>The efficient application of solar energy to realize photocatalytic biomass conversion to value-added chemicals is of significance. Herein, we propose a novel metal-free photocatalyst (4CzIPN@CMC-HG), which was prepared by encapsulating 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene (4CzIPN) in a carboxymethylcellulose-based hydrogel (CMC-HG) using a one-step thermal polymerization strategy. 4CzIPN@CMC-HG has an efficient photon-to-electron conversion rate, excellent visible light absorption, fast photogenerated carrier migration/separation, and high photocatalytic activity, with 90.7% yield of lactic acid (LA) and 100.0% conversion of xylose due to the synergistic effects between 4CzIPN and CMC-HG. 4CzIPN@CMC-HG showed remarkable universality and excellent stability, and the 1000-times amplification system indicated that this system has a potential industrial application in LA production. Furthermore, trapping experiments indicated that ˙OH, h + , 1 O 2 , and ˙O 2 − contributed to LA synthesis, with ˙O 2 − taking a leading role. These results showed the promising application prospects of metal-free photocatalysts in the photocatalytic biomass conversion to value-added chemicals.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/D2GC04336J</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Acid production ; Biomass ; Carbazole ; Carbazoles ; Carboxymethylcellulose ; Catalytic activity ; Conversion ; Electromagnetic absorption ; Encapsulation ; Green chemistry ; Hydrogels ; Industrial applications ; Lactic acid ; Photocatalysis ; Photocatalysts ; Solar energy ; Synergistic effect</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2023-01, Vol.25 (2), p.736-745</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3</citedby><cites>FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3</cites><orcidid>0000-0003-4088-6101 ; 0000-0002-1220-4065 ; 0000-0003-2721-6357 ; 0000-0002-2463-5794</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Sun, Shaofei</creatorcontrib><creatorcontrib>Sun, Shaochao</creatorcontrib><creatorcontrib>Liu, Kangning</creatorcontrib><creatorcontrib>Xiao, Ling-Ping</creatorcontrib><creatorcontrib>Ma, Jiliang</creatorcontrib><creatorcontrib>Sun, Runcang</creatorcontrib><title>Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>The efficient application of solar energy to realize photocatalytic biomass conversion to value-added chemicals is of significance. Herein, we propose a novel metal-free photocatalyst (4CzIPN@CMC-HG), which was prepared by encapsulating 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene (4CzIPN) in a carboxymethylcellulose-based hydrogel (CMC-HG) using a one-step thermal polymerization strategy. 4CzIPN@CMC-HG has an efficient photon-to-electron conversion rate, excellent visible light absorption, fast photogenerated carrier migration/separation, and high photocatalytic activity, with 90.7% yield of lactic acid (LA) and 100.0% conversion of xylose due to the synergistic effects between 4CzIPN and CMC-HG. 4CzIPN@CMC-HG showed remarkable universality and excellent stability, and the 1000-times amplification system indicated that this system has a potential industrial application in LA production. Furthermore, trapping experiments indicated that ˙OH, h + , 1 O 2 , and ˙O 2 − contributed to LA synthesis, with ˙O 2 − taking a leading role. These results showed the promising application prospects of metal-free photocatalysts in the photocatalytic biomass conversion to value-added chemicals.</description><subject>Acid production</subject><subject>Biomass</subject><subject>Carbazole</subject><subject>Carbazoles</subject><subject>Carboxymethylcellulose</subject><subject>Catalytic activity</subject><subject>Conversion</subject><subject>Electromagnetic absorption</subject><subject>Encapsulation</subject><subject>Green chemistry</subject><subject>Hydrogels</subject><subject>Industrial applications</subject><subject>Lactic acid</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Solar energy</subject><subject>Synergistic effect</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkV9rFDEUxQepYLv64icI9MXKRpNJJtl5LKtdlYIv-jzcZG7c2aaTNcmI00_ox2qWtX_gwrkXDud34FbVW84-cCbaj5_qzZpJIdS3F9Upl0rQttbs5HFX9avqLKUdY5xrJU-rf-swphwnm4cwkuAIkFvM4KmLiGS_DTlYKPecMvkzAMHRwj5NHh78fFkvxbKhGXOEmyG9sxAN3AWPtKWzv6ByqWg_2BnGYHC8wxHJMBbMwRf-zoW2nb1F7ycfElIDCXuynfsYfqEnLsTnLfJgiQd7ELBDT_Yx9Mfur6uXDnzCN_91Uf28-vxj_YVef998XV9eU8tXbaaCKa20Ubopg_2q0RIdk227km1jwbTaGddovnJYoxFOqV5x00vhOAMwRiyq82NuQf-eMOVuF6Y4FmRXl2QtSzArrvdHl40hpYiu28fhFuLccdYdPtU9fUrcA677iiY</recordid><startdate>20230123</startdate><enddate>20230123</enddate><creator>Sun, Shaofei</creator><creator>Sun, Shaochao</creator><creator>Liu, Kangning</creator><creator>Xiao, Ling-Ping</creator><creator>Ma, Jiliang</creator><creator>Sun, Runcang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4088-6101</orcidid><orcidid>https://orcid.org/0000-0002-1220-4065</orcidid><orcidid>https://orcid.org/0000-0003-2721-6357</orcidid><orcidid>https://orcid.org/0000-0002-2463-5794</orcidid></search><sort><creationdate>20230123</creationdate><title>Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production</title><author>Sun, Shaofei ; Sun, Shaochao ; Liu, Kangning ; Xiao, Ling-Ping ; Ma, Jiliang ; Sun, Runcang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acid production</topic><topic>Biomass</topic><topic>Carbazole</topic><topic>Carbazoles</topic><topic>Carboxymethylcellulose</topic><topic>Catalytic activity</topic><topic>Conversion</topic><topic>Electromagnetic absorption</topic><topic>Encapsulation</topic><topic>Green chemistry</topic><topic>Hydrogels</topic><topic>Industrial applications</topic><topic>Lactic acid</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Solar energy</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Shaofei</creatorcontrib><creatorcontrib>Sun, Shaochao</creatorcontrib><creatorcontrib>Liu, Kangning</creatorcontrib><creatorcontrib>Xiao, Ling-Ping</creatorcontrib><creatorcontrib>Ma, Jiliang</creatorcontrib><creatorcontrib>Sun, Runcang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Shaofei</au><au>Sun, Shaochao</au><au>Liu, Kangning</au><au>Xiao, Ling-Ping</au><au>Ma, Jiliang</au><au>Sun, Runcang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2023-01-23</date><risdate>2023</risdate><volume>25</volume><issue>2</issue><spage>736</spage><epage>745</epage><pages>736-745</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>The efficient application of solar energy to realize photocatalytic biomass conversion to value-added chemicals is of significance. Herein, we propose a novel metal-free photocatalyst (4CzIPN@CMC-HG), which was prepared by encapsulating 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene (4CzIPN) in a carboxymethylcellulose-based hydrogel (CMC-HG) using a one-step thermal polymerization strategy. 4CzIPN@CMC-HG has an efficient photon-to-electron conversion rate, excellent visible light absorption, fast photogenerated carrier migration/separation, and high photocatalytic activity, with 90.7% yield of lactic acid (LA) and 100.0% conversion of xylose due to the synergistic effects between 4CzIPN and CMC-HG. 4CzIPN@CMC-HG showed remarkable universality and excellent stability, and the 1000-times amplification system indicated that this system has a potential industrial application in LA production. Furthermore, trapping experiments indicated that ˙OH, h + , 1 O 2 , and ˙O 2 − contributed to LA synthesis, with ˙O 2 − taking a leading role. These results showed the promising application prospects of metal-free photocatalysts in the photocatalytic biomass conversion to value-added chemicals.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/D2GC04336J</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-4088-6101</orcidid><orcidid>https://orcid.org/0000-0002-1220-4065</orcidid><orcidid>https://orcid.org/0000-0003-2721-6357</orcidid><orcidid>https://orcid.org/0000-0002-2463-5794</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1463-9262
ispartof Green chemistry : an international journal and green chemistry resource : GC, 2023-01, Vol.25 (2), p.736-745
issn 1463-9262
1463-9270
language eng
recordid cdi_proquest_journals_2767745670
source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Acid production
Biomass
Carbazole
Carbazoles
Carboxymethylcellulose
Catalytic activity
Conversion
Electromagnetic absorption
Encapsulation
Green chemistry
Hydrogels
Industrial applications
Lactic acid
Photocatalysis
Photocatalysts
Solar energy
Synergistic effect
title Construction of a metal-free photocatalyst via encapsulation of 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene in a carboxymethylcellulose-based hydrogel for photocatalytic lactic acid production
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T21%3A51%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Construction%20of%20a%20metal-free%20photocatalyst%20via%20encapsulation%20of%201,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene%20in%20a%20carboxymethylcellulose-based%20hydrogel%20for%20photocatalytic%20lactic%20acid%20production&rft.jtitle=Green%20chemistry%20:%20an%20international%20journal%20and%20green%20chemistry%20resource%20:%20GC&rft.au=Sun,%20Shaofei&rft.date=2023-01-23&rft.volume=25&rft.issue=2&rft.spage=736&rft.epage=745&rft.pages=736-745&rft.issn=1463-9262&rft.eissn=1463-9270&rft_id=info:doi/10.1039/D2GC04336J&rft_dat=%3Cproquest_cross%3E2767745670%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c189t-306767b675675ed8574ef04998495cab97fbf5718fe2eb3f66d61bd43f10aabb3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2767745670&rft_id=info:pmid/&rfr_iscdi=true