A hybrid bonding strategy for tetrathiafulvalene-based hydrogen-bonded organic frameworks with electrical- and photo-conductivity

Two hybrid bonded hydrogen-bonded organic frameworks (namely PTP-HOF3 and PTP-HOF4) based on tetrathiafulvalene (TTF) exhibit good electrical- and photo-conductivity. PTP-HOF4 with proton transfer characteristics shows a more regular porosity with a size of 14.35 Å × 8.75 Å and better conductivity t...

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Bibliographic Details
Published in:CrystEngComm 2023-01, Vol.25 (4), p.58-512
Main Authors: Zhang, Yu, Hu, Li-Yuan, Luo, Xu-Feng, Shen, Liangjun, Li, Zhong-Qiu, Ke, Si-Wen, Li, Xing, Xiao, Xunwen
Format: Article
Language:English
Subjects:
Electrical resistivity
Hydrogen bonding
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Summary:Two hybrid bonded hydrogen-bonded organic frameworks (namely PTP-HOF3 and PTP-HOF4) based on tetrathiafulvalene (TTF) exhibit good electrical- and photo-conductivity. PTP-HOF4 with proton transfer characteristics shows a more regular porosity with a size of 14.35 Å × 8.75 Å and better conductivity than PTP-HOF3. The first proton transfer type HOF based on two-component TTF derivatives.
ISSN:1466-8033
1466-8033
DOI:10.1039/d2ce01614a