Fabrication of copper oxide nanoparticles immobilized onto deoxyribonucleic acid template: application for electrochemical detection of 2,4-dichlorophenoxyacetic acid

In the present research, a method for depositing copper oxide onto surface-attached deoxyribonucleic acid ( DNA) forming spherical nanoparticles for fabrication of a modified electrode (GCE/DNA/CuONPs) is presented. Scanning electron microscopy cyclic voltammetry and electrochemical impedance spectr...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Iranian Chemical Society 2023-02, Vol.20 (2), p.469-476
Main Authors: Amini, Nader, Maleki, Afshin, Rezaee, Reza, Shahmoradi, Behzad, Mohammadi, Ebrahim, Safari, Mahdi, Daraie, Huia
Format: Article
Language:English
Subjects:
Analytical Chemistry
Biochemistry
Chemistry
Chemistry and Materials Science
Copper oxides
Deoxyribonucleic acid
Dichlorophenoxyacetic acid
DNA
Electrical measurement
Electrochemical analysis
Electrochemical impedance spectroscopy
Electrodes
Herbicides
Inorganic Chemistry
Nanoparticles
Organic Chemistry
Original Paper
Physical Chemistry
Voltammetry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In the present research, a method for depositing copper oxide onto surface-attached deoxyribonucleic acid ( DNA) forming spherical nanoparticles for fabrication of a modified electrode (GCE/DNA/CuONPs) is presented. Scanning electron microscopy cyclic voltammetry and electrochemical impedance spectroscopy were used for characterization of the modification process. This electrode was used for the detection and determination of 2,4-dichlorophenoxyacetic acid (2,4-D) herbicide. For the first time, the electrooxidation of 2,4-D herbicide was investigated at two applied potentials by the proposed electrode. The electrochemical behaviors of this electrode were also studied by cyclic voltammetry and amperometry techniques. Based on the results, CuONPs and DNA exhibited a good electrocatalytic activity for the electrooxidation of 2,4-D herbicide. Many advantages were demonstrated by this research including application in sensitivities, linear ranges, and low detection of limits in two areas of potential for determination and detection of 2,4-D.
ISSN:1735-207X
1735-2428
DOI:10.1007/s13738-022-02679-5