Synthesis and Crystal Structure of a 3D Cd(II) Coordination Polymer Assembled with Itaconate and 1,2-Bis(4-pyridyl)ethane

The three-dimensional cadmium coordination polymer {[Cd 4 (H 2 O) 2 (ita) 4 (bpe) 6 ]⋅(H 2 O) 26 } n ( 1 ) (ita = itaconate; bpe = 1,2-bis(4-pyridyl)ethane) was obtained by self-assembly solution reaction under ambient conditions and characterized by elemental analysis, IR spectroscopy, and X-ray si...

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Bibliographic Details
Published in:Crystallography reports 2022-12, Vol.67 (7), p.1175-1182
Main Authors: García-Hernández, C., Téllez-López, A., Martínez-Otero, D., Sánchez-Mendieta, V.
Format: Article
Language:English
Subjects:
Coordination polymers
Crystal structure
Crystallography and Scattering Methods
Ethane
Infrared spectroscopy
Physics
Physics and Astronomy
Self-assembly
Single crystals
Structure of Organic Compounds
Topology
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Summary:The three-dimensional cadmium coordination polymer {[Cd 4 (H 2 O) 2 (ita) 4 (bpe) 6 ]⋅(H 2 O) 26 } n ( 1 ) (ita = itaconate; bpe = 1,2-bis(4-pyridyl)ethane) was obtained by self-assembly solution reaction under ambient conditions and characterized by elemental analysis, IR spectroscopy, and X-ray single crystal diffraction. Compound 1 crystallizes in the orthorhombic system with space group P 2 1 2 1 2 1 . Cd centers exhibit distorted octahedral and distorted pentagonal bipyramidal coordination geometries. Polymer 1 demonstrates a new 3D topology.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774522070033