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Lanthanum-Promoted Nickel-Based Catalysts for the Dry Reforming of Methane at Low Temperatures
In recent decades, considerable attention has been paid to the catalytic dry reforming of methane to obtain syngas. This reaction has very important environmental implications due to the utilization of CH 4 and CO 2 , gases that contribute to the greenhouse effect. The dry reforming of methane is no...
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Published in: | JOM (1989) 2023-03, Vol.75 (3), p.727-738 |
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description | In recent decades, considerable attention has been paid to the catalytic dry reforming of methane to obtain syngas. This reaction has very important environmental implications due to the utilization of CH
4
and CO
2
, gases that contribute to the greenhouse effect. The dry reforming of methane is normally carried out over strong basic catalysts with noble metals. Nickel has emerged as an interesting alternative, although it tends to deactivate and form carbon whiskers, which could block the reactor. It is therefore necessary to improve their catalytic performance (conversion, selectivity and stability). In this work, Ni
0.69
La
0.31
and Ni
0.14
Mg
0.55
La
0.31
were studied in the dry methane reforming reaction. The precursors were prepared by co-precipitation and the oxide phases were obtained by calcining these precursors at 450°C/6 h. The XRD diagrams of the calcined samples show the formation of mixed oxide phases with a periclase-like structure. Analysis of the temperature-programmed reduction shows that the presence of Mg shifts the reduction to higher temperatures. The catalysts, reduced at 650°C, were tested in this reaction as a function of operating time at 650°C. No deactivation occurred after 20 h of operation. Furthermore, the combination of Mg and La drastically improves the conversion and selectivity of the catalyst (> 95%). |
doi_str_mv | 10.1007/s11837-022-05619-z |
format | article |
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4
and CO
2
, gases that contribute to the greenhouse effect. The dry reforming of methane is normally carried out over strong basic catalysts with noble metals. Nickel has emerged as an interesting alternative, although it tends to deactivate and form carbon whiskers, which could block the reactor. It is therefore necessary to improve their catalytic performance (conversion, selectivity and stability). In this work, Ni
0.69
La
0.31
and Ni
0.14
Mg
0.55
La
0.31
were studied in the dry methane reforming reaction. The precursors were prepared by co-precipitation and the oxide phases were obtained by calcining these precursors at 450°C/6 h. The XRD diagrams of the calcined samples show the formation of mixed oxide phases with a periclase-like structure. Analysis of the temperature-programmed reduction shows that the presence of Mg shifts the reduction to higher temperatures. The catalysts, reduced at 650°C, were tested in this reaction as a function of operating time at 650°C. No deactivation occurred after 20 h of operation. Furthermore, the combination of Mg and La drastically improves the conversion and selectivity of the catalyst (> 95%).</description><identifier>ISSN: 1047-4838</identifier><identifier>EISSN: 1543-1851</identifier><identifier>DOI: 10.1007/s11837-022-05619-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Carbon dioxide ; Catalysts ; Catalytic converters ; Chemistry/Food Science ; Conversion ; Deactivation ; Earth Sciences ; Engineering ; Environment ; Greenhouse effect ; Lanthanum ; Low temperature ; Materials for Clean Energy Production and Storage ; Metals ; Methane ; Mixed oxides ; Nickel ; Noble metals ; Periclase ; Physics ; Precursors ; Reforming ; Roasting ; Selectivity ; Sintering ; Synthesis gas ; Temperature ; Whiskers (metals)</subject><ispartof>JOM (1989), 2023-03, Vol.75 (3), p.727-738</ispartof><rights>The Author(s) 2022</rights><rights>Copyright Springer Nature B.V. Mar 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c293t-24fbda55195484653fe7a3789b4d7334d914d453b41c6aecb2af986fa70334a73</citedby><cites>FETCH-LOGICAL-c293t-24fbda55195484653fe7a3789b4d7334d914d453b41c6aecb2af986fa70334a73</cites><orcidid>0000-0002-1907-9420 ; 0000-0002-8374-4384 ; 0000-0002-8979-3144 ; 0000-0001-9841-9157 ; 0000-0003-3183-1686</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Abdelsadek, Zoulikha</creatorcontrib><creatorcontrib>Köten, Hasan</creatorcontrib><creatorcontrib>Gonzalez-Cortes, Sergio</creatorcontrib><creatorcontrib>Cherifi, Ouiza</creatorcontrib><creatorcontrib>Halliche, Djamila</creatorcontrib><creatorcontrib>Masset, Patrick J.</creatorcontrib><title>Lanthanum-Promoted Nickel-Based Catalysts for the Dry Reforming of Methane at Low Temperatures</title><title>JOM (1989)</title><addtitle>JOM</addtitle><description>In recent decades, considerable attention has been paid to the catalytic dry reforming of methane to obtain syngas. This reaction has very important environmental implications due to the utilization of CH
4
and CO
2
, gases that contribute to the greenhouse effect. The dry reforming of methane is normally carried out over strong basic catalysts with noble metals. Nickel has emerged as an interesting alternative, although it tends to deactivate and form carbon whiskers, which could block the reactor. It is therefore necessary to improve their catalytic performance (conversion, selectivity and stability). In this work, Ni
0.69
La
0.31
and Ni
0.14
Mg
0.55
La
0.31
were studied in the dry methane reforming reaction. The precursors were prepared by co-precipitation and the oxide phases were obtained by calcining these precursors at 450°C/6 h. The XRD diagrams of the calcined samples show the formation of mixed oxide phases with a periclase-like structure. Analysis of the temperature-programmed reduction shows that the presence of Mg shifts the reduction to higher temperatures. The catalysts, reduced at 650°C, were tested in this reaction as a function of operating time at 650°C. No deactivation occurred after 20 h of operation. Furthermore, the combination of Mg and La drastically improves the conversion and selectivity of the catalyst (> 95%).</description><subject>Carbon dioxide</subject><subject>Catalysts</subject><subject>Catalytic converters</subject><subject>Chemistry/Food Science</subject><subject>Conversion</subject><subject>Deactivation</subject><subject>Earth Sciences</subject><subject>Engineering</subject><subject>Environment</subject><subject>Greenhouse effect</subject><subject>Lanthanum</subject><subject>Low temperature</subject><subject>Materials for Clean Energy Production and Storage</subject><subject>Metals</subject><subject>Methane</subject><subject>Mixed oxides</subject><subject>Nickel</subject><subject>Noble metals</subject><subject>Periclase</subject><subject>Physics</subject><subject>Precursors</subject><subject>Reforming</subject><subject>Roasting</subject><subject>Selectivity</subject><subject>Sintering</subject><subject>Synthesis gas</subject><subject>Temperature</subject><subject>Whiskers (metals)</subject><issn>1047-4838</issn><issn>1543-1851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kElPwzAQhSMEEqXwBzhZ4mzwGsdHKKsUFqFyxXISuwtNXGxHqP31uASJG3OZGc373kgvy04xOscIiYuAcUEFRIRAxHMs4XYvG2HOKMQFx_tpRkxAVtDiMDsKYYkSxCQeZe-l7uJcd30LX7xrXTQNeFrUH2YFr3RIy0RHvdqEGIB1HsS5Add-A15N2tpFNwPOgkezczBAR1C6LzA17dp4HXtvwnF2YPUqmJPfPs7ebm-mk3tYPt89TC5LWBNJIyTMVo3mHEvOCpZzao3QVBSyYo2glDUSs4ZxWjFc59rUFdFWFrnVAqWrFnScnQ2-a-8-exOiWrred-mlIiJVziTBSUUGVe1dCN5YtfaLVvuNwkjtclRDjirlqH5yVNsE0QEKSdzNjP-z_of6Bj2idis</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Abdelsadek, Zoulikha</creator><creator>Köten, Hasan</creator><creator>Gonzalez-Cortes, Sergio</creator><creator>Cherifi, Ouiza</creator><creator>Halliche, Djamila</creator><creator>Masset, Patrick J.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>4U-</scope><scope>7SR</scope><scope>7TA</scope><scope>7WY</scope><scope>7XB</scope><scope>883</scope><scope>88I</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>M0F</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0X</scope><orcidid>https://orcid.org/0000-0002-1907-9420</orcidid><orcidid>https://orcid.org/0000-0002-8374-4384</orcidid><orcidid>https://orcid.org/0000-0002-8979-3144</orcidid><orcidid>https://orcid.org/0000-0001-9841-9157</orcidid><orcidid>https://orcid.org/0000-0003-3183-1686</orcidid></search><sort><creationdate>20230301</creationdate><title>Lanthanum-Promoted Nickel-Based Catalysts for the Dry Reforming of Methane at Low Temperatures</title><author>Abdelsadek, Zoulikha ; Köten, Hasan ; Gonzalez-Cortes, Sergio ; Cherifi, Ouiza ; Halliche, Djamila ; Masset, Patrick J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-24fbda55195484653fe7a3789b4d7334d914d453b41c6aecb2af986fa70334a73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon dioxide</topic><topic>Catalysts</topic><topic>Catalytic converters</topic><topic>Chemistry/Food Science</topic><topic>Conversion</topic><topic>Deactivation</topic><topic>Earth Sciences</topic><topic>Engineering</topic><topic>Environment</topic><topic>Greenhouse effect</topic><topic>Lanthanum</topic><topic>Low temperature</topic><topic>Materials for Clean Energy Production and Storage</topic><topic>Metals</topic><topic>Methane</topic><topic>Mixed oxides</topic><topic>Nickel</topic><topic>Noble metals</topic><topic>Periclase</topic><topic>Physics</topic><topic>Precursors</topic><topic>Reforming</topic><topic>Roasting</topic><topic>Selectivity</topic><topic>Sintering</topic><topic>Synthesis gas</topic><topic>Temperature</topic><topic>Whiskers (metals)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdelsadek, Zoulikha</creatorcontrib><creatorcontrib>Köten, Hasan</creatorcontrib><creatorcontrib>Gonzalez-Cortes, Sergio</creatorcontrib><creatorcontrib>Cherifi, Ouiza</creatorcontrib><creatorcontrib>Halliche, Djamila</creatorcontrib><creatorcontrib>Masset, Patrick J.</creatorcontrib><collection>SpringerOpen</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>University Readers</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>ABI/INFORM Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Trade & Industry (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>JOM (1989)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdelsadek, Zoulikha</au><au>Köten, Hasan</au><au>Gonzalez-Cortes, Sergio</au><au>Cherifi, Ouiza</au><au>Halliche, Djamila</au><au>Masset, Patrick J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lanthanum-Promoted Nickel-Based Catalysts for the Dry Reforming of Methane at Low Temperatures</atitle><jtitle>JOM (1989)</jtitle><stitle>JOM</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>75</volume><issue>3</issue><spage>727</spage><epage>738</epage><pages>727-738</pages><issn>1047-4838</issn><eissn>1543-1851</eissn><abstract>In recent decades, considerable attention has been paid to the catalytic dry reforming of methane to obtain syngas. This reaction has very important environmental implications due to the utilization of CH
4
and CO
2
, gases that contribute to the greenhouse effect. The dry reforming of methane is normally carried out over strong basic catalysts with noble metals. Nickel has emerged as an interesting alternative, although it tends to deactivate and form carbon whiskers, which could block the reactor. It is therefore necessary to improve their catalytic performance (conversion, selectivity and stability). In this work, Ni
0.69
La
0.31
and Ni
0.14
Mg
0.55
La
0.31
were studied in the dry methane reforming reaction. The precursors were prepared by co-precipitation and the oxide phases were obtained by calcining these precursors at 450°C/6 h. The XRD diagrams of the calcined samples show the formation of mixed oxide phases with a periclase-like structure. Analysis of the temperature-programmed reduction shows that the presence of Mg shifts the reduction to higher temperatures. The catalysts, reduced at 650°C, were tested in this reaction as a function of operating time at 650°C. No deactivation occurred after 20 h of operation. Furthermore, the combination of Mg and La drastically improves the conversion and selectivity of the catalyst (> 95%).</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11837-022-05619-z</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-1907-9420</orcidid><orcidid>https://orcid.org/0000-0002-8374-4384</orcidid><orcidid>https://orcid.org/0000-0002-8979-3144</orcidid><orcidid>https://orcid.org/0000-0001-9841-9157</orcidid><orcidid>https://orcid.org/0000-0003-3183-1686</orcidid><oa>free_for_read</oa></addata></record> |
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source | Springer Nature |
subjects | Carbon dioxide Catalysts Catalytic converters Chemistry/Food Science Conversion Deactivation Earth Sciences Engineering Environment Greenhouse effect Lanthanum Low temperature Materials for Clean Energy Production and Storage Metals Methane Mixed oxides Nickel Noble metals Periclase Physics Precursors Reforming Roasting Selectivity Sintering Synthesis gas Temperature Whiskers (metals) |
title | Lanthanum-Promoted Nickel-Based Catalysts for the Dry Reforming of Methane at Low Temperatures |
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