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Ultrathin Conversion Coatings on AMg3 Aluminum Alloy. Part 1. Optimization of the Coating-Fabrication Process
—The decrease of the corrosion resistance of aluminum alloys of different doping systems results from their phase and surface heterogeneity. Operation in environments of various aggressiveness contributes to the emergence of local types of corrosion damage on aluminum alloys. This results in prematu...
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Published in: | Protection of metals and physical chemistry of surfaces 2022-12, Vol.58 (7), p.1295-1300 |
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creator | Kuzenkov, Yu. A. Oleinik, S. V. Nyrkov, N. P. Arkhipushkin, I. A. |
description | —The decrease of the corrosion resistance of aluminum alloys of different doping systems results from their phase and surface heterogeneity. Operation in environments of various aggressiveness contributes to the emergence of local types of corrosion damage on aluminum alloys. This results in premature failure of metal structures. A rather wide range of coatings are used to protect aluminum alloys, among which conversion coatings occupy a significant share due to their production effectiveness and compatibility with many paint systems. In this regard, the possibility of fabrication of submicron protective conversion coatings on AMg3 aluminum alloy in molybdenum converting media has been studied in this work. Electrochemical studies have shown that the addition of ammonium nitrate to the molybdenum-converting compound does not affect subsequent treatment (filling) of the resulting coatings in a corrosion-inhibitor solution. The optimal time for fabrication of coatings and its subsequent filling has been revealed. It has been shown that the studied molybdenum-conversion coatings are similar in protective properties to the traditional chromate coating. |
doi_str_mv | 10.1134/S2070205122070073 |
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In this regard, the possibility of fabrication of submicron protective conversion coatings on AMg3 aluminum alloy in molybdenum converting media has been studied in this work. Electrochemical studies have shown that the addition of ammonium nitrate to the molybdenum-converting compound does not affect subsequent treatment (filling) of the resulting coatings in a corrosion-inhibitor solution. The optimal time for fabrication of coatings and its subsequent filling has been revealed. 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ISSN 2070-2051, Protection of Metals and Physical Chemistry of Surfaces, 2022, Vol. 58, No. 7, pp. 1295–1300. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2021, published in Korroziya: Materialy, Zashchita, 2021, No. 5, pp. 42–47.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-2744f6b2afccd1da973c0799fc4523de31aa8276a766e6c50beea95d32159fd13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Kuzenkov, Yu. A.</creatorcontrib><creatorcontrib>Oleinik, S. V.</creatorcontrib><creatorcontrib>Nyrkov, N. P.</creatorcontrib><creatorcontrib>Arkhipushkin, I. A.</creatorcontrib><title>Ultrathin Conversion Coatings on AMg3 Aluminum Alloy. Part 1. Optimization of the Coating-Fabrication Process</title><title>Protection of metals and physical chemistry of surfaces</title><addtitle>Prot Met Phys Chem Surf</addtitle><description>—The decrease of the corrosion resistance of aluminum alloys of different doping systems results from their phase and surface heterogeneity. Operation in environments of various aggressiveness contributes to the emergence of local types of corrosion damage on aluminum alloys. This results in premature failure of metal structures. A rather wide range of coatings are used to protect aluminum alloys, among which conversion coatings occupy a significant share due to their production effectiveness and compatibility with many paint systems. In this regard, the possibility of fabrication of submicron protective conversion coatings on AMg3 aluminum alloy in molybdenum converting media has been studied in this work. Electrochemical studies have shown that the addition of ammonium nitrate to the molybdenum-converting compound does not affect subsequent treatment (filling) of the resulting coatings in a corrosion-inhibitor solution. The optimal time for fabrication of coatings and its subsequent filling has been revealed. It has been shown that the studied molybdenum-conversion coatings are similar in protective properties to the traditional chromate coating.</description><subject>Alloys</subject><subject>Aluminum alloys</subject><subject>Aluminum base alloys</subject><subject>Ammonium nitrate</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Chromate coatings</subject><subject>Chromating</subject><subject>Conversion coatings</subject><subject>Corrosion</subject><subject>Corrosion and Coatings</subject><subject>Corrosion inhibitors</subject><subject>Corrosion resistance</subject><subject>Heterogeneity</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Molybdenum</subject><subject>Optimization</subject><subject>Protective Coatings</subject><subject>System effectiveness</subject><subject>Tribology</subject><issn>2070-2051</issn><issn>2070-206X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhoMoOKc_wLuC1535aD56OYZTYbKBDrwrWZpuGW0zk1SYv96U-nEhXp0HzvOeAy8A1whOECLZ7TOGHGJIEe4BcnICRj2lGLLX0x-m6BxceL-HkDEu-Ag06zo4GXamTWa2fdfOG9ujDKbd-iTy9GlLkmndNabtmgi1PU6SlXQhQZNkeQimMR_RjqatkrDT3-F0LjfOqGG1clZp7y_BWSVrr6--5his53cvs4d0sbx_nE0XqcJMhBTzLKvYBstKqRKVMudEQZ7nlcooJqUmSEqBOZOcMc0UhRutZU5LghHNqxKRMbgZ7h6cfeu0D8Xedq6NLwvMBRRICEajhQZLOeu901VxcKaR7lggWPStFn9ajRk8ZHx02612v5f_D30CaCt4_Q</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Kuzenkov, Yu. 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subjects | Alloys Aluminum alloys Aluminum base alloys Ammonium nitrate Characterization and Evaluation of Materials Chemistry and Materials Science Chromate coatings Chromating Conversion coatings Corrosion Corrosion and Coatings Corrosion inhibitors Corrosion resistance Heterogeneity Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Metallic Materials Molybdenum Optimization Protective Coatings System effectiveness Tribology |
title | Ultrathin Conversion Coatings on AMg3 Aluminum Alloy. Part 1. Optimization of the Coating-Fabrication Process |
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