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2D Honeycomb Coordination Polymers from 2,2′-Dithiobis(pyridine N-oxide) and Bismuth(III) Halides
Two bismuth(III) coordination polymers, namely [Bi 2 X 6 ( µ -dtpo) 3 ] n [ X = Cl ( 1) , Br ( 2 ); dtpo = 2,2′-dithiobis(pyridine N -oxide)], were prepared using a crystal engineering strategy and structurally characterized by X-ray crystallography. In the isostructural compounds 1 and 2 (trigonal...
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| Published in: | Journal of chemical crystallography 2023-03, Vol.53 (1), p.105-111 |
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| creator | Seidel, Rüdiger W. Oppel, Iris M. |
| description | Two bismuth(III) coordination polymers, namely [Bi
2
X
6
(
µ
-dtpo)
3
]
n
[
X
= Cl (
1)
, Br (
2
); dtpo = 2,2′-dithiobis(pyridine
N
-oxide)], were prepared using a crystal engineering strategy and structurally characterized by X-ray crystallography. In the isostructural compounds
1
and
2
(trigonal system, space group
P
-3
c
1),
fac
-configured Bi
X
3
units as nodes are joined by the
C
2
-symmetrical dtpo bridging ligand as spacers to generate 2D honeycomb layers with (6,3) topology. The 2D sheets stack along the [001] direction, resulting in virtually hexagonal channels parallel to this direction, which are occupied by disordered methanol and water molecules. The potential solvent area per unit cell volume is 42.2% for
1
and 44.0% for
2
.
Graphical Abstract
Two isostructural 2D honeycomb bismuth(III) coordination, synthesized from 2,2′-dithiobis(pyridine
N
-oxide) and bismuth(III) halides are described. |
| doi_str_mv | 10.1007/s10870-022-00949-x |
| format | article |
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2
X
6
(
µ
-dtpo)
3
]
n
[
X
= Cl (
1)
, Br (
2
); dtpo = 2,2′-dithiobis(pyridine
N
-oxide)], were prepared using a crystal engineering strategy and structurally characterized by X-ray crystallography. In the isostructural compounds
1
and
2
(trigonal system, space group
P
-3
c
1),
fac
-configured Bi
X
3
units as nodes are joined by the
C
2
-symmetrical dtpo bridging ligand as spacers to generate 2D honeycomb layers with (6,3) topology. The 2D sheets stack along the [001] direction, resulting in virtually hexagonal channels parallel to this direction, which are occupied by disordered methanol and water molecules. The potential solvent area per unit cell volume is 42.2% for
1
and 44.0% for
2
.
Graphical Abstract
Two isostructural 2D honeycomb bismuth(III) coordination, synthesized from 2,2′-dithiobis(pyridine
N
-oxide) and bismuth(III) halides are described.</description><identifier>ISSN: 1074-1542</identifier><identifier>EISSN: 1572-8854</identifier><identifier>DOI: 10.1007/s10870-022-00949-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Bismuth ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Crystallography ; Crystallography and Scattering Methods ; Halides ; Inorganic Chemistry ; Organometallic Chemistry ; Original Paper ; Physical Chemistry ; Pyridines ; Topology ; Unit cell</subject><ispartof>Journal of chemical crystallography, 2023-03, Vol.53 (1), p.105-111</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-cd351812bd5b55743ffb41c14d5fee903009b0f1fa1e1f5a4e453f6183ec50953</citedby><cites>FETCH-LOGICAL-c249t-cd351812bd5b55743ffb41c14d5fee903009b0f1fa1e1f5a4e453f6183ec50953</cites><orcidid>0000-0003-3438-4666</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Seidel, Rüdiger W.</creatorcontrib><creatorcontrib>Oppel, Iris M.</creatorcontrib><title>2D Honeycomb Coordination Polymers from 2,2′-Dithiobis(pyridine N-oxide) and Bismuth(III) Halides</title><title>Journal of chemical crystallography</title><addtitle>J Chem Crystallogr</addtitle><description>Two bismuth(III) coordination polymers, namely [Bi
2
X
6
(
µ
-dtpo)
3
]
n
[
X
= Cl (
1)
, Br (
2
); dtpo = 2,2′-dithiobis(pyridine
N
-oxide)], were prepared using a crystal engineering strategy and structurally characterized by X-ray crystallography. In the isostructural compounds
1
and
2
(trigonal system, space group
P
-3
c
1),
fac
-configured Bi
X
3
units as nodes are joined by the
C
2
-symmetrical dtpo bridging ligand as spacers to generate 2D honeycomb layers with (6,3) topology. The 2D sheets stack along the [001] direction, resulting in virtually hexagonal channels parallel to this direction, which are occupied by disordered methanol and water molecules. The potential solvent area per unit cell volume is 42.2% for
1
and 44.0% for
2
.
Graphical Abstract
Two isostructural 2D honeycomb bismuth(III) coordination, synthesized from 2,2′-dithiobis(pyridine
N
-oxide) and bismuth(III) halides are described.</description><subject>Bismuth</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Crystallography</subject><subject>Crystallography and Scattering Methods</subject><subject>Halides</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Pyridines</subject><subject>Topology</subject><subject>Unit cell</subject><issn>1074-1542</issn><issn>1572-8854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kM9KAzEQh4MoWKsv4CngpYLRSTbpZo_aql0o6kHPYf8kNqW7qckWujefyUfySYxW8OZpBub7zQwfQqcULilAehUoyBQIMEYAMp6R7R4aUJEyIqXg-7GHlBMqODtERyEsIVKSpQNUsSmeuVb3lWtKPHHO17YtOuta_ORWfaN9wMa7BrML9vn-Qaa2W1hX2jBa995GVuMH4ra21ue4aGt8Y0Oz6RajPM_P8axYxUE4RgemWAV98luH6OXu9nkyI_PH-3xyPScV41lHqjoRVFJW1qIUIuWJMSWnFeW1MFpnkMSfSzDUFFRTIwquuUjMmMpEVwIykQzR2W7v2ru3jQ6dWrqNb-NJxVJJx5kACZFiO6ryLgSvjVp72xS-VxTUt0y1k6miTPUjU21jKNmFQoTbV-3_Vv-T-gKryXeu</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Seidel, Rüdiger W.</creator><creator>Oppel, Iris M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3438-4666</orcidid></search><sort><creationdate>20230301</creationdate><title>2D Honeycomb Coordination Polymers from 2,2′-Dithiobis(pyridine N-oxide) and Bismuth(III) Halides</title><author>Seidel, Rüdiger W. ; Oppel, Iris M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-cd351812bd5b55743ffb41c14d5fee903009b0f1fa1e1f5a4e453f6183ec50953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Bismuth</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Crystallography</topic><topic>Crystallography and Scattering Methods</topic><topic>Halides</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Pyridines</topic><topic>Topology</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seidel, Rüdiger W.</creatorcontrib><creatorcontrib>Oppel, Iris M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seidel, Rüdiger W.</au><au>Oppel, Iris M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>2D Honeycomb Coordination Polymers from 2,2′-Dithiobis(pyridine N-oxide) and Bismuth(III) Halides</atitle><jtitle>Journal of chemical crystallography</jtitle><stitle>J Chem Crystallogr</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>53</volume><issue>1</issue><spage>105</spage><epage>111</epage><pages>105-111</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><abstract>Two bismuth(III) coordination polymers, namely [Bi
2
X
6
(
µ
-dtpo)
3
]
n
[
X
= Cl (
1)
, Br (
2
); dtpo = 2,2′-dithiobis(pyridine
N
-oxide)], were prepared using a crystal engineering strategy and structurally characterized by X-ray crystallography. In the isostructural compounds
1
and
2
(trigonal system, space group
P
-3
c
1),
fac
-configured Bi
X
3
units as nodes are joined by the
C
2
-symmetrical dtpo bridging ligand as spacers to generate 2D honeycomb layers with (6,3) topology. The 2D sheets stack along the [001] direction, resulting in virtually hexagonal channels parallel to this direction, which are occupied by disordered methanol and water molecules. The potential solvent area per unit cell volume is 42.2% for
1
and 44.0% for
2
.
Graphical Abstract
Two isostructural 2D honeycomb bismuth(III) coordination, synthesized from 2,2′-dithiobis(pyridine
N
-oxide) and bismuth(III) halides are described.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10870-022-00949-x</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-3438-4666</orcidid></addata></record> |
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| issn | 1074-1542 1572-8854 |
| language | eng |
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| source | Springer Nature |
| subjects | Bismuth Chemistry Chemistry and Materials Science Coordination polymers Crystallography Crystallography and Scattering Methods Halides Inorganic Chemistry Organometallic Chemistry Original Paper Physical Chemistry Pyridines Topology Unit cell |
| title | 2D Honeycomb Coordination Polymers from 2,2′-Dithiobis(pyridine N-oxide) and Bismuth(III) Halides |
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