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A Diamidocarbene-Supported Aminoborylene: Characterization and Discussion of the Elusive Crystal Structure
Five years after we published the synthesis of the first diamidocarbene (DAC)-supported amino borylene 4 , we now report the elusive single crystal X-ray structure. The X-ray structure of 4 was found to corroborate our previous computational studies which indicated that the borylene adopted a hetero...
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| Published in: | Journal of chemical crystallography 2023-03, Vol.53 (1), p.112-116 |
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| Main Authors: | , , |
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| Language: | English |
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| container_title | Journal of chemical crystallography |
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| creator | Ledet, Anthony D. Reinheimer, Eric W. Hudnall, Todd W. |
| description | Five years after we published the synthesis of the first diamidocarbene (DAC)-supported amino borylene
4
, we now report the elusive single crystal X-ray structure. The X-ray structure of
4
was found to corroborate our previous computational studies which indicated that the borylene adopted a heterocumulenic geometry with a near linear C
(carbene)
= B = N unit (175.88(18)
◦
) as well as short C = B and B = N distances of 1.416(3) and 1.344(3) Å, respectively. Additionally, we further provide a qualitative and quantitative discourse on said structure with respect to the precursor compounds used to prepare
4
as well as to the known cyclic (alkyl) amino carbene (CAAC) analog
2. |
| doi_str_mv | 10.1007/s10870-022-00950-4 |
| format | article |
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4
, we now report the elusive single crystal X-ray structure. The X-ray structure of
4
was found to corroborate our previous computational studies which indicated that the borylene adopted a heterocumulenic geometry with a near linear C
(carbene)
= B = N unit (175.88(18)
◦
) as well as short C = B and B = N distances of 1.416(3) and 1.344(3) Å, respectively. Additionally, we further provide a qualitative and quantitative discourse on said structure with respect to the precursor compounds used to prepare
4
as well as to the known cyclic (alkyl) amino carbene (CAAC) analog
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4
, we now report the elusive single crystal X-ray structure. The X-ray structure of
4
was found to corroborate our previous computational studies which indicated that the borylene adopted a heterocumulenic geometry with a near linear C
(carbene)
= B = N unit (175.88(18)
◦
) as well as short C = B and B = N distances of 1.416(3) and 1.344(3) Å, respectively. Additionally, we further provide a qualitative and quantitative discourse on said structure with respect to the precursor compounds used to prepare
4
as well as to the known cyclic (alkyl) amino carbene (CAAC) analog
2.</description><subject>Carbenes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallography and Scattering Methods</subject><subject>Crystals</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Structure</subject><issn>1074-1542</issn><issn>1572-8854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU1PwzAMhisEEmPwBzhV4pyRpGnTcpvG-JCQOAzOUZq6W6auGUmKNH49HkXiRnxIbL2PY-tNkmtGZ4xSeRsYLSUllHNCaZVTIk6SCcslJ2WZi1N8UykIywU_Ty5C2FJUlVxOku08vbd6ZxtntK-hB7Ia9nvnIzTpfGd7Vzt_6LB-ly422msTwdsvHa3rU903CAczhHBMXZvGDaTLbgj2E9KFP4Sou3QV_WDi4OEyOWt1F-Dq954m7w_Lt8UTeXl9fF7MX4jhMhMkg9Zo1jRMA2dctyWnkjNT0qZllairWrOaFmUlTY476QLzQuChwBGFPJsmN2PfvXcfA4Sotm7wPX6puCxZUeVVlaFqNqrWugNl-9ZF3A6jgZ01rofWYn0us0qITHCGAB8B410IHlq193an_UExqo4mqNEEhSaoHxOUQCgboYDifg3-b5Z_qG90y4q-</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Ledet, Anthony D.</creator><creator>Reinheimer, Eric W.</creator><creator>Hudnall, Todd W.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9260-2986</orcidid></search><sort><creationdate>20230301</creationdate><title>A Diamidocarbene-Supported Aminoborylene: Characterization and Discussion of the Elusive Crystal Structure</title><author>Ledet, Anthony D. ; Reinheimer, Eric W. ; Hudnall, Todd W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2734-3efca1dd1ae212af820721c80df194b9ba1b06897c5074a6ba1644440e23efe53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbenes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallography and Scattering Methods</topic><topic>Crystals</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ledet, Anthony D.</creatorcontrib><creatorcontrib>Reinheimer, Eric W.</creatorcontrib><creatorcontrib>Hudnall, Todd W.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ledet, Anthony D.</au><au>Reinheimer, Eric W.</au><au>Hudnall, Todd W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Diamidocarbene-Supported Aminoborylene: Characterization and Discussion of the Elusive Crystal Structure</atitle><jtitle>Journal of chemical crystallography</jtitle><stitle>J Chem Crystallogr</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>53</volume><issue>1</issue><spage>112</spage><epage>116</epage><pages>112-116</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><abstract>Five years after we published the synthesis of the first diamidocarbene (DAC)-supported amino borylene
4
, we now report the elusive single crystal X-ray structure. The X-ray structure of
4
was found to corroborate our previous computational studies which indicated that the borylene adopted a heterocumulenic geometry with a near linear C
(carbene)
= B = N unit (175.88(18)
◦
) as well as short C = B and B = N distances of 1.416(3) and 1.344(3) Å, respectively. Additionally, we further provide a qualitative and quantitative discourse on said structure with respect to the precursor compounds used to prepare
4
as well as to the known cyclic (alkyl) amino carbene (CAAC) analog
2.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10870-022-00950-4</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-9260-2986</orcidid></addata></record> |
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| subjects | Carbenes Chemistry Chemistry and Materials Science Crystal structure Crystallography and Scattering Methods Crystals Inorganic Chemistry Organometallic Chemistry Original Paper Physical Chemistry Single crystals Structure |
| title | A Diamidocarbene-Supported Aminoborylene: Characterization and Discussion of the Elusive Crystal Structure |
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