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Switchable surface activity of Bi2Al4O9 nano particles: A contemporary approach in heterocyclic synthesis
Ferroelectric catalysis is emerging as an efficient chemical transformation strategy, especially in the field of clean energy production, wastewater treatment and degradation of pollutants. The core of ferroelectric catalysis is the dynamically switchable electrical polarization on their surface. It...
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| Published in: | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2023-03, Vol.25 (3), p.49, Article 49 |
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| container_issue | 3 |
| container_start_page | 49 |
| container_title | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology |
| container_volume | 25 |
| creator | Mishra, Manisha Jomon, K. J. Chinnam, Sampath Devasia, Jyothis Nizam, Aatika Reddy, M. B. Madhusudana |
| description | Ferroelectric catalysis is emerging as an efficient chemical transformation strategy, especially in the field of clean energy production, wastewater treatment and degradation of pollutants. The core of ferroelectric catalysis is the dynamically switchable electrical polarization on their surface. It enables them to switch their surface activity, more precisely due to binding strength with the substrate. Even though a plethora of reports are available, the introduction of ferroelectric catalytic surfaces for the generation of heterocyclic compounds is a novel aspect. Here, we introduce ferroelectric Bismuthaluminate nanoparticles as catalysts for generating derivatives of azalactone, tetrahydro-benzopyran and pyranopyrazole with improved catalytic efficiency. This can be achieved by switching the direction of polarization of the catalyst which indeed alters the surface electronic states and stimulates the reaction followed by the excellent yield. Here the switchable property is due to the thermally induced polarization of water.
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| doi_str_mv | 10.1007/s11051-023-05703-8 |
| format | article |
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| subjects | Catalysis Catalysts Characterization and Evaluation of Materials Chemical synthesis Chemistry Chemistry and Materials Science Clean energy Efficiency Electric fields Electron states Energy Ferroelectric materials Ferroelectricity Heterocyclic compounds Induced polarization Inorganic Chemistry Lasers Materials Science Nanoparticles Nanotechnology Optical Devices Optics Photonics Physical Chemistry Polarization Pollutants Research Paper Solvents Substrates Surface activity Wastewater treatment |
| title | Switchable surface activity of Bi2Al4O9 nano particles: A contemporary approach in heterocyclic synthesis |
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