Conversion degree and heat transfer in the cold cap and their effect on glass production rate in an electric melter

• Published in: International journal of applied glass science 2023-04, Vol.14 (2), p.318-329
• Main Authors: Ferkl, Pavel, Hrma, Pavel, Abboud, Alexander, Guillen, Donna Post, Vernerová, Miroslava, Kloužek, Jaroslav, Hall, Mark, Kruger, Albert A., Pokorný, Richard
• Format: Article
• Language: English
• Subjects: batch reactions; Computational fluid dynamics; Conversion; Heat transfer; Material properties; modeling; nuclear waste; Power consumption; Prediction models; Radioactive wastes; reaction kinetics; Vitrification
• ISSN: 2041-1286; 2041-1294
• DOI: 10.1111/ijag.16615

A predictive model of melt rate in waste glass vitrification operations is needed to inform melter operations during normal and off‐normal operations. This paper describes the development of a model of the cold cap (the reacting melter feed floating on molten glass in a glass melter) that couples heat transfer with the feed‐to‐glass conversion kinetics. The model was applied to four melter feeds designed for high‐level and low‐activity nuclear waste feeds using the material properties, either measured or estimated, to obtain temperature and conversion distribution within the cold cap. The cold cap model, when coupled with a computational fluid dynamics model of a Joule‐heated glass melter, allows the prediction of the glass production rate and power consumption. The results show reasonable agreement with the melting rates measured during pilot‐scale melter tests.