COMPARATIVE XPS STUDY OF THE COMPOSITION AND ELECTRONIC STATE OF IRIDIUM IN BULK AND IMMOBILIZED BINUCLEAR [Ir(COD)Cl]2 COMPLEXES

Changes in the composition and electronic state of iridium in the [Ir(COD)Cl] 2 complex, which are induced by X-ray radiation and oxidation by atmospheric oxygen, are studied by XPS.

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Bibliographic Details
Published in:Journal of structural chemistry 2023-02, Vol.64 (2), p.270-275
Main Authors: Kvon, R. I., Nartova, A. V., Kovtunova, L. M., Bukhtiyarov, V. I.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Composition
Electron states
Inorganic Chemistry
Iridium
Molecular
Optical and Plasma Physics
Oxidation
Physical Chemistry
Solid State Physics
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Description
Summary:Changes in the composition and electronic state of iridium in the [Ir(COD)Cl] 2 complex, which are induced by X-ray radiation and oxidation by atmospheric oxygen, are studied by XPS.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476623020117