Loading…
Kinetics of the liquid-phase oxidation of cyclooctene in the presence of MnO2
The kinetics of the liquid-phase oxidation of cyclooctene by molecular oxygen in the presence of a MnC2 catalyst is studied. It is found that MnC2 is an initiator of this reaction and has no effect on the steps of chain propagation and termination. The oxidation occurs by a radical chain mechanism w...
Saved in:
Published in: | Kinetics and catalysis 2000-07, Vol.41 (4), p.457-461 |
---|---|
Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | The kinetics of the liquid-phase oxidation of cyclooctene by molecular oxygen in the presence of a MnC2 catalyst is studied. It is found that MnC2 is an initiator of this reaction and has no effect on the steps of chain propagation and termination. The oxidation occurs by a radical chain mechanism with the escape of radicals to the bulk of the reaction mixture. Radicals are formed by the interaction of the olefin with the solid catalyst surface. The kinetic parameters of the reaction are calculated. |
---|---|
ISSN: | 0023-1584 1608-3210 |
DOI: | 10.1007/BF02756062 |