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On the Wigner-Witmer correlation rules for a homonuclear diatomic molecule with the like atoms in identical atomic states

The problem of building the manifold of electronic states of a homonuclear diatomic molecule formed from two like atoms in identical atomic states is readdressed. A conceptually simple approach is presented by invoking a model and all the standard results originally obtained by Wigner and Witmer are...

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Bibliographic Details
Published in:Pramāṇa 1998-09, Vol.51 (3-4), p.445-452
Main Authors: Bellary, V. P., Balasubramanian, T. K., Shetty, B. J.
Format: Article
Language:English
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Summary:The problem of building the manifold of electronic states of a homonuclear diatomic molecule formed from two like atoms in identical atomic states is readdressed. A conceptually simple approach is presented by invoking a model and all the standard results originally obtained by Wigner and Witmer are reproduced.
ISSN:0304-4289
0973-7111
DOI:10.1007/BF02828937