Influence of composite mixtures between nematic liquid crystal and porous carbon nanoparticles towards photoluminescence and UV absorbance

• Published in: Applied physics. A, Materials science & processing Materials science & processing, 2023-04, Vol.129 (4), Article 261
• Main Authors: Pathak, Govind, Rujiralai, Thitima, Hegde, Gurumurthy, Manohar, Rajiv
• Format: Article
• Language: English
• Subjects: Absorbance; Absorptivity; Applied physics; Carbon; Characterization and Evaluation of Materials; Condensed Matter Physics; Dispersion; Dopants; Energy gap; Liquid crystal displays; Machines; Manufacturing; Materials science; Nanoparticles; Nanotechnology; Nematic crystals; Optical and Electronic Materials; Optical density; Optical properties; Parameters; Photoluminescence; Physics; Physics and Astronomy; Porous materials; Processes; Surfaces and Interfaces; Thin Films
• ISSN: 0947-8396; 1432-0630
• DOI: 10.1007/s00339-023-06550-z

The optical parameters of the liquid crystalline materials can be tuned by the dispersion of nanoparticles. Concentration of dopant in the host LC material affects its optical properties significantly, which makes the dispersed system suitable for LC-based devices. In the present investigation, we have studied the effect of different concentrations of nanoparticles on the optical properties of LC, as a guest–host system, where PCNP is guest material and NLC is host material. Porous carbon nanoparticles (PCNPs) were dispersed into the nematic liquid crystal (NLC) in three different concentrations. Optical parameters were measured for pure NLC and NLC-PCNP composites. Photoluminescence (PL) study was performed and it was found that the PL intensity increased for the PCNP dispersed system. High photoluminescence has much importance in the luminescent displays. Full width half maxima (FWHM) were also determined by the Gaussian fitting of PL intensity data. UV absorbance was also measured which gets increased for the PCNP dispersed NLC system when compared to pure NLC. Optical bandgap was found to be reduced after the dispersion of PCNP into NLC. Several other parameters such as absorption coefficient and optical density were also determined. The proposed work may be significant for the liquid crystal displays (LCDs) and other devices which require less bandgap materials. This work may also put some light on the effect of dopants on the LC material in the research based on guest–host system. Increasing the photoluminescence and creating less bandgap materials using carbon nanoparticles is a real challenge, and porous nanoparticles used here overcome this challenge.