Enhancing the activity and stability of Cu2O nanorods via coupling with a NaNbO3/SnS2 heterostructure for photoelectrochemical water-splitting

• Published in: New journal of chemistry 2023-03, Vol.47 (13), p.6294-6304
• Main Authors: Tiwari, Shalini, Yadav, Priyanka, Ganguli, Ashok K
• Format: Article
• Language: English
• Subjects: Alignment; Charge transfer; Copper oxides; Current carriers; Electrochemical impedance spectroscopy; Heterojunctions; Heterostructures; Nanorods; Photoelectric effect; Sodium compounds; Tin disulfide; Water splitting
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/d3nj00684k

Fabrication of a NaNbO3/SnS2/Cu2O heterostructure was undertaken for the application of photoelectrochemical water-splitting. A type-II band alignment for charge carrier migration (i.e., electrons and holes) provided a high rate of charge transfer at the interface of the heterostructure, which aided prevention of photocorrosion and broadened the absorption range from the ultraviolet region to the visible region. Type-II band alignment was created in a NaNbO3/SnS2 heterojunction. Another type-II band alignment was formed in SnS2/Cu2O with a n–p-type heterojunction. Linear sweep voltammetry (LSV) plots of the NaNbO3/SnS2/Cu2O heterostructure showed higher photocurrent density at a low onset potential. Mott–Schottky plots confirmed formation of a n–n–p heterojunction in the composition of NaNbO3/SnS2/Cu2O, which helps to lower the recombination rate of charge carriers. Electrochemical impedance spectroscopy (EIS) suggested a smaller value of charge transfer resistance of the NaNbO3/SnS2/Cu2O heterostructure; these data supported the evidence that migration of charge carriers was much more favorable in the designed heterostructure, which exhibited higher activity towards photoelectrochemical water-splitting.