Synthesis, structures, and characterizations of four uranyl coordination polymers constructed by mixed-ligand strategy

Uranyl coordination polymers have caught more and more attention due to their rich topological structures and potential practical applications in nuclear waste processing and management. In this work, four novel uranyl coordination polymers have been successfully synthesized by the utilization of a...

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Bibliographic Details
Published in:Journal of radioanalytical and nuclear chemistry 2023-04, Vol.332 (4), p.1367-1376
Main Authors: Chen, Si-han, Wang, Han-qing
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination polymers
Diagnostic Radiology
Hadrons
Heavy Ions
Hydrothermal reactions
Inorganic Chemistry
Ligands
Luminescence
Nuclear Chemistry
Nuclear Physics
Optical properties
Physical Chemistry
Polymer industry
Polymers
Radioactive wastes
Succinic acid
Waste disposal
X ray powder diffraction
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Summary:Uranyl coordination polymers have caught more and more attention due to their rich topological structures and potential practical applications in nuclear waste processing and management. In this work, four novel uranyl coordination polymers have been successfully synthesized by the utilization of a semirigid ligand and uranyl nitrate under hydrothermal reactions through the introducing of different kinds of auxiliary ligands (NaCl, oxalate acid, succinic acid). Therein, the powder X-ray diffraction, Infrared spectroscopy and luminescence properties of compounds 3 and 4 are investigated.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-022-08758-4