Comparative study on the corrosion behaviour of CNT-reinforced NiAl alloys in NaCl and Na2SO4 solutions

• Published in: Journal of materials science 2023-04, Vol.58 (14), p.6329-6342
• Main Authors: Netshia, Mukhethwa, Mahlobo, Mandlenkosi G. R., Awotunde, Mary A., Olubambi, Peter A.
• Format: Article
• Language: English
• Subjects: Alloys; Aluminum oxide; Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Comparative studies; Corrosion; Corrosion products; Corrosion rate; Corrosion resistance; Corrosion tests; Crystallography and Scattering Methods; Intermetallic compounds; Materials Science; Metals & Corrosion; Nickel aluminides; Nickel base alloys; Nickel compounds; Polymer Sciences; Reinforcement; Sodium chloride; Solid Mechanics
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-023-08405-7

Various electrochemical techniques were used to study the corrosion behaviour of the CNT-reinforced NiAl alloys under NaCl and Na 2 SO 4 environments. The potentiodynamic polarization curves revealed activation Tafel behaviour when the NiAl alloy specimens were immersed in NaCl solution while passivation followed by slight development of transpassivation resulted under Na 2 SO 4 environment. The reinforcement of pure NiAl alloy with up to 1.0 wt.% CNT increased the corrosion rate from 0.10 to 0.63 mm/yr under NaCl environment, while under Na 2 SO 4 environment, the corrosion rate increased from 0.04 to 0.12 mm/yr. The observed increase in corrosion rate with an increase in CNT reinforcement (under both NaCl and Na 2 SO 4 environments) suggested that the reinforcement of NiAl alloys with CNT reduced the corrosion resistance of NiAl. The X-ray diffraction analysis revealed that the corrosion products consisted of oxides including Al 2 O 3 under NaCl environment, while scanning electron microscope analysis showed a porous passive layer on the surface of the alloy specimens immersed in Na 2 SO 4 solution. Graphical abstract