Dual colorimetric and fluorometric monitoring of Cd2+ and Hg2+ ions in water using functionalized Zrmetal–organic frameworks chemosensors

• Published in: Applied organometallic chemistry 2023-05, Vol.37 (5), p.n/a
• Main Authors: El‐Bindarya, Mohamed A., Shahat, Ahmed, El‐Deen, Ibrahim M., Khalil, Muhammad A., Hassan, Nader
• Format: Article
• Language: English
• Subjects: Cadmium; Chemical sensors; Chemistry; Chemoreceptors; chemo‐sensor; Colorimetry; Drinking water; fluorescent; Fourier transforms; Mercury (metal); metal ions detection; Metal-organic frameworks; metal–organic framework; Photoelectrons; Sensors; spectrophotometry; Water sampling; Zirconium
• ISSN: 0268-2605; 1099-0739
• DOI: 10.1002/aoc.7070

Chemical sensor based on NH2‐UiO‐66(Zr) have been developed for rapid detection of Cd2+ and Hg2+ ions. The developed 2HA = N‐UiO‐66(Zr) sensor was prepared by the condensation of the Zr‐metal–organic framework (MOF) with 2‐hydroxyacetophenone. The NH2‐UiO‐66(Zr) and 2HA = N‐UiO‐66(Zr) sensor were characterized by scanning electron microscopy (SEM), X‐ray diffractometer (XRD), Fourier transform infrared (FT‐IR), X‐ray photoelectron spectroscopy (XPS), and Brunner–Emmet–Teller (BET). The characterization results shown that 2‐hydroxyacetophenone was successfully introduced on the Zr‐based MOF and that the pore structure of 2HA = N‐UiO‐66(Zr) sensor mainly contains mesopores. Many experimental studies have been conducted to find out the optimum conditions for colorimetric and fluorometric determining of the Cd2+ and Hg2+ ions by the 2HA = N‐UiO‐66(Zr) sensor. The response time, for the sensor, that is necessary to achieve a steady spectroscopic signal was less than 30 s. The suggested methods were validated in terms of the lowest limit of detection (LOD), the lowest limit of quantification (LOQ), linearity, and precision according to International Conference on Harmonization (ICH) guidelines. As a result, the 2HA = N‐UiO‐66(Zr) sensor was successfully used to determine Cd2+ and Hg2+ ions in a variety of tap water samples with great sensitivity and selectivity. A novel sensor, 2HA = N‐UiO‐66(Zr), was successfully synthesized by post‐modifying NH2‐UiO‐66(Zr) with 2‐hydroxyacetophenone and applied in the selective and sensitive colorimetric and fluorometric detection of Cd2+ and Hg2+ from aqueous solution. The 2HA = N‐UiO‐66(Zr) sensor was characterized by scanning electron microscopy (SEM), X‐ray diffractometer (XRD), Fourier transform infrared (FT‐IR), X‐ray photoelectron spectroscopy (XPS), and Brunner–Emmet–Teller (BET). The characterization results shown that 2‐Hydroxyacetophenone was successfully introduced on the zirconium‐based metal–organic framework (MOF) and that the pore structure of 2HA = N‐UiO‐66(Zr) sensor mainly contains mesopores. A real metallized industrial wastewater sample was investigated against a synthesized sensor with a powerful metal's removal efficiency.