Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)

The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have bee...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of general chemistry 2023-03, Vol.93 (3), p.575-585
Main Author: Smirnov, P. R.
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c307t-70ecc46101de24b93811b6fe9bc389b451d1ef621b63ced5f17f3df4f0dfaf7f3
container_end_page 585
container_issue 3
container_start_page 575
container_title Russian journal of general chemistry
container_volume 93
creator Smirnov, P. R.
description The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.
doi_str_mv 10.1134/S1070363223030143
format article
fullrecord <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2805488579</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A746918321</galeid><sourcerecordid>A746918321</sourcerecordid><originalsourceid>FETCH-LOGICAL-c307t-70ecc46101de24b93811b6fe9bc389b451d1ef621b63ced5f17f3df4f0dfaf7f3</originalsourceid><addsrcrecordid>eNp1kU1LAzEQhhdRsFZ_gLeAFz2szmz281hK1UJV8AOPS5qdaEqb1CRb8d-bUsGDSA55mXmfmUkmSU4RLhF5fvWEUAEveZZx4IA530sGWEKdcl7AftQxnW7zh8mR9wsABCizQRLGdrUWTgS9ITZ-j0oGctoHLT2zioV3YvckHPnAJmajnTUrMoE9BdfL0Mf41nVHQSzZ1BrPtGGvIpZgwnRsJClYo4PTS2LnI_ZIG02fF8fJgRJLTyc_9zB5uZ48j2_T2cPNdDyapZJDFdIKSMq8RMCOsnze8BpxXipq5pLXzTwvsENSZRaDXFJXKKwU71SuoFNCRT1MznZ1185-9PEJ7cL2zsSWbVZDkdd1UTXRdblzvYkltdooG-IvxNPRSktrSMXp21GVlw3WPMMI4A6QznrvSLVrp1fCfbUI7XYb7Z9tRCbbMT56zRu531H-h74BYyKMPg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2805488579</pqid></control><display><type>article</type><title>Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)</title><source>Springer Nature</source><creator>Smirnov, P. R.</creator><creatorcontrib>Smirnov, P. R.</creatorcontrib><description>The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363223030143</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acetonitrile ; Aqueous solutions ; Cations ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Comparative analysis ; Nitrogen ; Solvation ; Solvents</subject><ispartof>Russian journal of general chemistry, 2023-03, Vol.93 (3), p.575-585</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>COPYRIGHT 2023 Springer</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c307t-70ecc46101de24b93811b6fe9bc389b451d1ef621b63ced5f17f3df4f0dfaf7f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Smirnov, P. R.</creatorcontrib><title>Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.</description><subject>Acetonitrile</subject><subject>Aqueous solutions</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Comparative analysis</subject><subject>Nitrogen</subject><subject>Solvation</subject><subject>Solvents</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kU1LAzEQhhdRsFZ_gLeAFz2szmz281hK1UJV8AOPS5qdaEqb1CRb8d-bUsGDSA55mXmfmUkmSU4RLhF5fvWEUAEveZZx4IA530sGWEKdcl7AftQxnW7zh8mR9wsABCizQRLGdrUWTgS9ITZ-j0oGctoHLT2zioV3YvckHPnAJmajnTUrMoE9BdfL0Mf41nVHQSzZ1BrPtGGvIpZgwnRsJClYo4PTS2LnI_ZIG02fF8fJgRJLTyc_9zB5uZ48j2_T2cPNdDyapZJDFdIKSMq8RMCOsnze8BpxXipq5pLXzTwvsENSZRaDXFJXKKwU71SuoFNCRT1MznZ1185-9PEJ7cL2zsSWbVZDkdd1UTXRdblzvYkltdooG-IvxNPRSktrSMXp21GVlw3WPMMI4A6QznrvSLVrp1fCfbUI7XYb7Z9tRCbbMT56zRu531H-h74BYyKMPg</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Smirnov, P. R.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230301</creationdate><title>Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)</title><author>Smirnov, P. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-70ecc46101de24b93811b6fe9bc389b451d1ef621b63ced5f17f3df4f0dfaf7f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acetonitrile</topic><topic>Aqueous solutions</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Comparative analysis</topic><topic>Nitrogen</topic><topic>Solvation</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Smirnov, P. R.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Smirnov, P. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>93</volume><issue>3</issue><spage>575</spage><epage>585</epage><pages>575-585</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363223030143</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1070-3632
ispartof Russian journal of general chemistry, 2023-03, Vol.93 (3), p.575-585
issn 1070-3632
1608-3350
language eng
recordid cdi_proquest_journals_2805488579
source Springer Nature
subjects Acetonitrile
Aqueous solutions
Cations
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Comparative analysis
Nitrogen
Solvation
Solvents
title Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-17T00%3A34%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Comparative%20Characteristics%20of%20the%20Nearest%20Environment%20Structures%20of%20Metal%20Ions%20in%20Water%20and%20Acetonitrile%20(A%20Review)&rft.jtitle=Russian%20journal%20of%20general%20chemistry&rft.au=Smirnov,%20P.%20R.&rft.date=2023-03-01&rft.volume=93&rft.issue=3&rft.spage=575&rft.epage=585&rft.pages=575-585&rft.issn=1070-3632&rft.eissn=1608-3350&rft_id=info:doi/10.1134/S1070363223030143&rft_dat=%3Cgale_proqu%3EA746918321%3C/gale_proqu%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c307t-70ecc46101de24b93811b6fe9bc389b451d1ef621b63ced5f17f3df4f0dfaf7f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2805488579&rft_id=info:pmid/&rft_galeid=A746918321&rfr_iscdi=true