Study of the Photoreaction of Methyladamantylthione Using Chemical Nuclear Polarization

The article presents the results of our study of the mechanisms of the photoreactions of methyladamantylthione AdCSCH 3 ( I ) using chemical nuclear polarization (CNP) effects, which show themselves in the NMR spectra. While pulsed and laser photolysis allows us to study the kinetics of death and ac...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2023-03, Vol.97 (3), p.521-524
Main Authors: Porkhun, V. I., Kuznetsova, N. A., Savelyev, E. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Magnetochemistry
Mechanochemistry
NMR
Nuclear magnetic resonance
Photochemistry
Photolysis
Physical Chemistry
Polarization
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Summary:The article presents the results of our study of the mechanisms of the photoreactions of methyladamantylthione AdCSCH 3 ( I ) using chemical nuclear polarization (CNP) effects, which show themselves in the NMR spectra. While pulsed and laser photolysis allows us to study the kinetics of death and accumulation of intermediates released from the solvent cell, the use of CNP allows us to study cell processes in detail. The elementary acts of the reaction were established and proved experimentally.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024423030226