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Improvement of the Structural and Electrical Properties of the Proton-Conducting PVA-NH4NO3 Solid Polymer Electrolyte System by Incorporating Nanosized Anatase TiO2 Single-Crystal
A proton-conducting nanocomposite polymer electrolyte (NCPE) system, based on polyvinyl alcohol (PVA) as the host polymer and ammonium nitrate (NH 4 NO 3 ) as the proton source, has been prepared with different concentrations of nanosized titanium dioxide (TiO 2 ) by solution casting. The changes in...
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| Published in: | Journal of electronic materials 2023-06, Vol.52 (6), p.3921-3930 |
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| cites | cdi_FETCH-LOGICAL-c319t-adac0e836622844d9716481526b7d9d52d9006f366b40d22597017daf543dc8d3 |
| container_end_page | 3930 |
| container_issue | 6 |
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| creator | Abdullah, Omed Gh Mustafa, Bakhan S. Bdewi, Shahbaa F. Ahmed, Hawzhin T. Mohamad, Azhin H. Suhail, Mahdi H. |
| description | A proton-conducting nanocomposite polymer electrolyte (NCPE) system, based on polyvinyl alcohol (PVA) as the host polymer and ammonium nitrate (NH
4
NO
3
) as the proton source, has been prepared with different concentrations of nanosized titanium dioxide (TiO
2
) by solution casting. The changes in the structural features related to the electrical properties have been studied using XRD analysis, which revealed that the NCPE sample with 8 wt.% TiO
2
NPs exhibits the highest amorphous content. The addition of single-crystal TiO
2
NPs to the proton-conducting polymer electrolyte has resulted in a remarkable enhancement of the ionic conductivity of the system. A maximum DC conductivity of 5.52 × 10
−3
S cm
−1
at 303 K has been achieved for the NCPE containing 8 wt.% of TiO
2
NPs. The temperature-dependent ionic conductivity was displayed in a typical Vogel–Tammann–Fulcher-type equation, indicating a direct correlation between ionic conductivity and segmental movements of the PVA chains. The AC conductivity spectra of NCPEs have been studied in terms of the universal power law of Jonscher, and the dielectric relaxation phenomenon was analyzed using electric modulus formalism to assess if the relaxation is Debye or non-Debye type. |
| doi_str_mv | 10.1007/s11664-023-10399-6 |
| format | article |
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4
NO
3
) as the proton source, has been prepared with different concentrations of nanosized titanium dioxide (TiO
2
) by solution casting. The changes in the structural features related to the electrical properties have been studied using XRD analysis, which revealed that the NCPE sample with 8 wt.% TiO
2
NPs exhibits the highest amorphous content. The addition of single-crystal TiO
2
NPs to the proton-conducting polymer electrolyte has resulted in a remarkable enhancement of the ionic conductivity of the system. A maximum DC conductivity of 5.52 × 10
−3
S cm
−1
at 303 K has been achieved for the NCPE containing 8 wt.% of TiO
2
NPs. The temperature-dependent ionic conductivity was displayed in a typical Vogel–Tammann–Fulcher-type equation, indicating a direct correlation between ionic conductivity and segmental movements of the PVA chains. The AC conductivity spectra of NCPEs have been studied in terms of the universal power law of Jonscher, and the dielectric relaxation phenomenon was analyzed using electric modulus formalism to assess if the relaxation is Debye or non-Debye type.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-023-10399-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Ammonium nitrate ; Anatase ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Conducting polymers ; Dielectric relaxation ; Electrical properties ; Electrolytes ; Electronics and Microelectronics ; Instrumentation ; Ion currents ; Ions ; Materials Science ; Nanocomposites ; Optical and Electronic Materials ; Original Research Article ; Polymers ; Polyvinyl alcohol ; Protons ; Single crystals ; Solid State Physics ; Temperature dependence ; Titanium dioxide</subject><ispartof>Journal of electronic materials, 2023-06, Vol.52 (6), p.3921-3930</ispartof><rights>The Minerals, Metals & Materials Society 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-adac0e836622844d9716481526b7d9d52d9006f366b40d22597017daf543dc8d3</citedby><cites>FETCH-LOGICAL-c319t-adac0e836622844d9716481526b7d9d52d9006f366b40d22597017daf543dc8d3</cites><orcidid>0000-0002-1914-152X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Abdullah, Omed Gh</creatorcontrib><creatorcontrib>Mustafa, Bakhan S.</creatorcontrib><creatorcontrib>Bdewi, Shahbaa F.</creatorcontrib><creatorcontrib>Ahmed, Hawzhin T.</creatorcontrib><creatorcontrib>Mohamad, Azhin H.</creatorcontrib><creatorcontrib>Suhail, Mahdi H.</creatorcontrib><title>Improvement of the Structural and Electrical Properties of the Proton-Conducting PVA-NH4NO3 Solid Polymer Electrolyte System by Incorporating Nanosized Anatase TiO2 Single-Crystal</title><title>Journal of electronic materials</title><addtitle>J. Electron. Mater</addtitle><description>A proton-conducting nanocomposite polymer electrolyte (NCPE) system, based on polyvinyl alcohol (PVA) as the host polymer and ammonium nitrate (NH
4
NO
3
) as the proton source, has been prepared with different concentrations of nanosized titanium dioxide (TiO
2
) by solution casting. The changes in the structural features related to the electrical properties have been studied using XRD analysis, which revealed that the NCPE sample with 8 wt.% TiO
2
NPs exhibits the highest amorphous content. The addition of single-crystal TiO
2
NPs to the proton-conducting polymer electrolyte has resulted in a remarkable enhancement of the ionic conductivity of the system. A maximum DC conductivity of 5.52 × 10
−3
S cm
−1
at 303 K has been achieved for the NCPE containing 8 wt.% of TiO
2
NPs. The temperature-dependent ionic conductivity was displayed in a typical Vogel–Tammann–Fulcher-type equation, indicating a direct correlation between ionic conductivity and segmental movements of the PVA chains. The AC conductivity spectra of NCPEs have been studied in terms of the universal power law of Jonscher, and the dielectric relaxation phenomenon was analyzed using electric modulus formalism to assess if the relaxation is Debye or non-Debye type.</description><subject>Ammonium nitrate</subject><subject>Anatase</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Conducting polymers</subject><subject>Dielectric relaxation</subject><subject>Electrical properties</subject><subject>Electrolytes</subject><subject>Electronics and Microelectronics</subject><subject>Instrumentation</subject><subject>Ion currents</subject><subject>Ions</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Optical and Electronic Materials</subject><subject>Original Research Article</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Protons</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Temperature dependence</subject><subject>Titanium dioxide</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kc1KAzEUhYMoWH9ewFXAdTR_k5lZllJtQdpCq7gL6SSjU2aSmqTC-Fq-oNFW3LkKJ_d858I9AFwRfEMwzm8DIUJwhClDBLOyROIIDEjGkyzE8zEYYCYIyijLTsFZCBuMSUYKMgCf027r3bvpjI3Q1TC-GriMflfFnVctVFbDcWuq6JsqyYV3W-NjY8KvN_1EZ9HIWZ2Yxr7AxdMQzSZ8Nmdw6dpGw4Vr-874Q04SMa3oQzQdXPdwaivnt86rH3imrAvNh9FwaFVUwcBVM6dwmWatQSOfMNVegJNatcFcHt5z8Hg3Xo0m6GF-Px0NH1DFSBmR0qrCpmBCUFpwrsucCF6QjIp1rkudUV1iLOo0X3OsKc3KHJNcqzqdTVeFZufgep-bLvS2MyHKjdt5m1ZKWhCcM8Y5Sy66d1XeheBNLbe-6ZTvJcHyuxy5L0emcuRPOVIkiO2hkMz2xfi_6H-oL_mOlBI</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Abdullah, Omed Gh</creator><creator>Mustafa, Bakhan S.</creator><creator>Bdewi, Shahbaa F.</creator><creator>Ahmed, Hawzhin T.</creator><creator>Mohamad, Azhin H.</creator><creator>Suhail, Mahdi H.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope><orcidid>https://orcid.org/0000-0002-1914-152X</orcidid></search><sort><creationdate>20230601</creationdate><title>Improvement of the Structural and Electrical Properties of the Proton-Conducting PVA-NH4NO3 Solid Polymer Electrolyte System by Incorporating Nanosized Anatase TiO2 Single-Crystal</title><author>Abdullah, Omed Gh ; Mustafa, Bakhan S. ; Bdewi, Shahbaa F. ; Ahmed, Hawzhin T. ; Mohamad, Azhin H. ; Suhail, Mahdi H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-adac0e836622844d9716481526b7d9d52d9006f366b40d22597017daf543dc8d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Ammonium nitrate</topic><topic>Anatase</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Conducting polymers</topic><topic>Dielectric relaxation</topic><topic>Electrical properties</topic><topic>Electrolytes</topic><topic>Electronics and Microelectronics</topic><topic>Instrumentation</topic><topic>Ion currents</topic><topic>Ions</topic><topic>Materials Science</topic><topic>Nanocomposites</topic><topic>Optical and Electronic Materials</topic><topic>Original Research Article</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Protons</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Temperature dependence</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdullah, Omed Gh</creatorcontrib><creatorcontrib>Mustafa, Bakhan S.</creatorcontrib><creatorcontrib>Bdewi, Shahbaa F.</creatorcontrib><creatorcontrib>Ahmed, Hawzhin T.</creatorcontrib><creatorcontrib>Mohamad, Azhin H.</creatorcontrib><creatorcontrib>Suhail, Mahdi H.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest research library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>ProQuest advanced technologies & aerospace journals</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdullah, Omed Gh</au><au>Mustafa, Bakhan S.</au><au>Bdewi, Shahbaa F.</au><au>Ahmed, Hawzhin T.</au><au>Mohamad, Azhin H.</au><au>Suhail, Mahdi H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improvement of the Structural and Electrical Properties of the Proton-Conducting PVA-NH4NO3 Solid Polymer Electrolyte System by Incorporating Nanosized Anatase TiO2 Single-Crystal</atitle><jtitle>Journal of electronic materials</jtitle><stitle>J. Electron. Mater</stitle><date>2023-06-01</date><risdate>2023</risdate><volume>52</volume><issue>6</issue><spage>3921</spage><epage>3930</epage><pages>3921-3930</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><abstract>A proton-conducting nanocomposite polymer electrolyte (NCPE) system, based on polyvinyl alcohol (PVA) as the host polymer and ammonium nitrate (NH
4
NO
3
) as the proton source, has been prepared with different concentrations of nanosized titanium dioxide (TiO
2
) by solution casting. The changes in the structural features related to the electrical properties have been studied using XRD analysis, which revealed that the NCPE sample with 8 wt.% TiO
2
NPs exhibits the highest amorphous content. The addition of single-crystal TiO
2
NPs to the proton-conducting polymer electrolyte has resulted in a remarkable enhancement of the ionic conductivity of the system. A maximum DC conductivity of 5.52 × 10
−3
S cm
−1
at 303 K has been achieved for the NCPE containing 8 wt.% of TiO
2
NPs. The temperature-dependent ionic conductivity was displayed in a typical Vogel–Tammann–Fulcher-type equation, indicating a direct correlation between ionic conductivity and segmental movements of the PVA chains. The AC conductivity spectra of NCPEs have been studied in terms of the universal power law of Jonscher, and the dielectric relaxation phenomenon was analyzed using electric modulus formalism to assess if the relaxation is Debye or non-Debye type.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-023-10399-6</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-1914-152X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0361-5235 |
| ispartof | Journal of electronic materials, 2023-06, Vol.52 (6), p.3921-3930 |
| issn | 0361-5235 1543-186X |
| language | eng |
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| source | Springer Nature |
| subjects | Ammonium nitrate Anatase Characterization and Evaluation of Materials Chemistry and Materials Science Conducting polymers Dielectric relaxation Electrical properties Electrolytes Electronics and Microelectronics Instrumentation Ion currents Ions Materials Science Nanocomposites Optical and Electronic Materials Original Research Article Polymers Polyvinyl alcohol Protons Single crystals Solid State Physics Temperature dependence Titanium dioxide |
| title | Improvement of the Structural and Electrical Properties of the Proton-Conducting PVA-NH4NO3 Solid Polymer Electrolyte System by Incorporating Nanosized Anatase TiO2 Single-Crystal |
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