Physico-chemical Characteristics of Biodegradable Poly(lactic acid) and Poly(lactic acid)/Chitosan Nano-Composites Under the Influence of Gamma Irradiation

• Published in: Journal of polymers and the environment 2023-06, Vol.31 (6), p.2705-2714
• Main Authors: Elsawy, Moataz A., Fekry, Mohamed, Sayed, Aisha M., Maziad, Nabila A., Saad, Gamal R.
• Format: Article
• Language: English
• Subjects: Biodegradation; Chain scission; Chemistry; Chemistry and Materials Science; Chitosan; Chloroform; Crystallization; Degradation; Elongation; Environmental Chemistry; Environmental Engineering/Biotechnology; Food irradiation; Gamma irradiation; Glass transition temperature; Industrial Chemistry/Chemical Engineering; Irradiation; Materials Science; Melt temperature; Molecular weight; Nanocomposites; Nanoparticles; Original Paper; Polylactic acid; Polymer Sciences; Radiation dosage; Temperature; Tensile strength; Tensile tests; Thermal stability; Transition temperatures; γ Radiation
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-022-02693-x

PLA and its nanocomposite containing 3% chitosan nanoparticles (PLA-3CsNP) were studied to see how γ -irradiation affected their characteristics. Different doses of γ -irradiation were applied to the investigated materials under inquiry (5–40 kGy) using 60 Co at ambient conditions. The irradiation materials were characterized by FT-IR, GPC, mechanical tensile test, DSC, XRD, and TGA in solid and chloroform solutions. The molecular weight of the studied materials was lowered when the irradiation dose was increased, indicating that γ-irradiation had the dominating effect through oxidative degradation, and chain scission. The addition of chitosan to PLA reduces the impact of γ-irradiation, while the samples irradiated in solution showed more degradation after irradiation than irradiated solid films. Irradiation caused a decrease in tensile strength and elongation at break values. Both the melting temperature (Tm) and the glass transition temperature (Tg) decreased as the irradiation dose was increased. The crystallization peak temperatures were reduced when pure PLA was irradiated in solution. The thermal stability of PLA was diminished as the irradiation dose was raised, and this effect was more pronounced in samples irradiated in chloroform solution.