Synthesis, characterization and antibacterial activity of some transition metal complexes of a new dioxime ligand

A new ligand containing a dioxime derivatives, (H2L) (1) Namely P-phenylenediamine – N, N’-bis (2-butylidine -3- one oxime) has been prepared by condensation reaction of 2,3-butanedion mono oxime (2) with 1,4 – diaminobenzene. The titled ligand (H2L) was used to prepare some metal ions complexes nam...

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Bibliographic Details
Main Authors: Rahman, Abdul Salam Abdul Kareem Abdul, Hussien, Nasry Jassim, Abdullah, Khalid Tuama, Fakhar, Imran, Yusof, Siti Fairus M., Yousif, Enaam Ismail
Format: Conference Proceeding
Language:English
Subjects:
Coordination compounds
Copper
Ligands
Melting points
Nickel
Phenylenediamine
Transition metal compounds
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Summary:A new ligand containing a dioxime derivatives, (H2L) (1) Namely P-phenylenediamine – N, N’-bis (2-butylidine -3- one oxime) has been prepared by condensation reaction of 2,3-butanedion mono oxime (2) with 1,4 – diaminobenzene. The titled ligand (H2L) was used to prepare some metal ions complexes namely Co(II), Ni(II) and Cu(II). This ligand and its complexes were confirmed by F.T.-i.r., (U.V-Vis.), mass spectroscopy, (1H, 13CNMR) and elemental micro analysis (C.H.N), molar conductance, element content and melting point measurement. It was concluded that the geometry around Cu(II) and Co(II) complexes were distorted tetrahedral geometry while Ni(II) complex was a square planer.
ISSN:0094-243X
1551-7616
DOI:10.1063/5.0113082