Tuning the functionality of metal–organic frameworks (MOFs) for fuel cells and hydrogen storage applications

Metal–organic frameworks (MOFs) are porous crystalline materials with exceptional properties. The tremendous synthetic tunability of MOFs has emerged to be beneficial for many applications. This review study discusses the roles of MOFs in hydrogen fuel cell technology, including the synthesis of oxy...

Full description

Saved in:
Bibliographic Details
Published in:Journal of materials science 2023-06, Vol.58 (21), p.8637-8677
Main Authors: Wong, Chun Yik, Wong, Wai Yin, Sudarsono, Wulandhari, Loh, Kee Shyuan, Lim, Kean Long, Bo, Wu
Format: Article
Language:English
Subjects:
Carbon
Catalysis
Characterization and Evaluation of Materials
Chemical synthesis
Chemistry and Materials Science
Classical Mechanics
Clean technology
Crystallography and Scattering Methods
Electrochemical analysis
Electrolytes
Electrolytic cells
Energy
Fuel cell industry
Fuel cells
Functional groups
Hydrogen
Hydrogen as fuel
Hydrogen fuels
Hydrogen storage materials
Ligands
Materials Science
Membranes
Metal-organic frameworks
Polymer Sciences
Polymers
Porosity
Porous materials
Review
Solid Mechanics
Technology application
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Metal–organic frameworks (MOFs) are porous crystalline materials with exceptional properties. The tremendous synthetic tunability of MOFs has emerged to be beneficial for many applications. This review study discusses the roles of MOFs in hydrogen fuel cell technology, including the synthesis of oxygen reduction catalysts, hydrogen storage materials, and ion carriers for polymer electrolyte membranes (PEMs). Various chemical modification approaches have been identified, namely: (1) confinement of guest species into the pores of MOFs, (2) modification of the organic ligands with functional groups, and (3) carbonization of MOFs. The tunable properties of MOFs have offered an improvement toward their desired application. The primary properties are surface area, which correlates with the availability of active sites that lead to an improvement in electrochemical performance. Finally, the outline concerning commercializing fuel cell technologies with MOFs is tabulated along with a future perspective in addressing some of the current limitations in the studies. Graphical Abstract
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-023-08552-x