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Investigation on the Explosion Process and Chemical Activity of Pyrite Dust
The explosion process and chemical activity of pyrite dust were investigated by explosion test, thermo-gravimetric analysis and FactSage numerical simulation. Based on the results of tests and simulation of pyrite dust explosion, a numerical model was developed to reveal the explosion process. The r...
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Published in: | Russian Journal of Physical Chemistry A 2023-05, Vol.97 (5), p.894-901 |
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container_title | Russian Journal of Physical Chemistry A |
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creator | Rao, Yunzhang Huang, Tao Tian, Changshun Xiang, Cairong Su, Gang |
description | The explosion process and chemical activity of pyrite dust were investigated by explosion test, thermo-gravimetric analysis and FactSage numerical simulation. Based on the results of tests and simulation of pyrite dust explosion, a numerical model was developed to reveal the explosion process. The results indicate that the explosion process is controlled by heterogeneous combustion and the volatilization of sulfur oxides leads to weight loss of pyrite dust. In addition, the explosion severity is dominated by the sulfur content, and the apparent activity energy of pyrite dust decreases with the sulfur content increasing, resulting in enhancing chemical activity and weight loss. Compared to pyrrhotite dust explosion, pyrite is less susceptible to oxidation, but pyrite dust is more explosive. |
doi_str_mv | 10.1134/S003602442305031X |
format | article |
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Based on the results of tests and simulation of pyrite dust explosion, a numerical model was developed to reveal the explosion process. The results indicate that the explosion process is controlled by heterogeneous combustion and the volatilization of sulfur oxides leads to weight loss of pyrite dust. In addition, the explosion severity is dominated by the sulfur content, and the apparent activity energy of pyrite dust decreases with the sulfur content increasing, resulting in enhancing chemical activity and weight loss. Compared to pyrrhotite dust explosion, pyrite is less susceptible to oxidation, but pyrite dust is more explosive.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S003602442305031X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical activity ; Chemical Kinetics and Catalysis ; Chemistry ; Chemistry and Materials Science ; Dust ; Mathematical models ; Numerical models ; Oxidation ; Physical Chemistry ; Pyrite ; Pyrrhotite ; Sulfur oxides ; Thermogravimetric analysis ; Weight loss</subject><ispartof>Russian Journal of Physical Chemistry A, 2023-05, Vol.97 (5), p.894-901</ispartof><rights>Pleiades Publishing, Ltd. 2023. 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Chem</addtitle><description>The explosion process and chemical activity of pyrite dust were investigated by explosion test, thermo-gravimetric analysis and FactSage numerical simulation. Based on the results of tests and simulation of pyrite dust explosion, a numerical model was developed to reveal the explosion process. The results indicate that the explosion process is controlled by heterogeneous combustion and the volatilization of sulfur oxides leads to weight loss of pyrite dust. In addition, the explosion severity is dominated by the sulfur content, and the apparent activity energy of pyrite dust decreases with the sulfur content increasing, resulting in enhancing chemical activity and weight loss. Compared to pyrrhotite dust explosion, pyrite is less susceptible to oxidation, but pyrite dust is more explosive.</description><subject>Chemical activity</subject><subject>Chemical Kinetics and Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dust</subject><subject>Mathematical models</subject><subject>Numerical models</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Pyrite</subject><subject>Pyrrhotite</subject><subject>Sulfur oxides</subject><subject>Thermogravimetric analysis</subject><subject>Weight loss</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UEtLAzEQDqJgrf4AbwHPq3nMZrPHUl_FggUVeluy2Wyb0m5qkhb7781SwYMIAwPzPWbmQ-iakltKOdy9EcIFYQCMk5xwOj9BA5pzmknB56do0MNZj5-jixBWhAAAhQF6mXR7E6JdqGhdh1PFpcEPX9u1C_1g5p02IWDVNXi8NBur1RqPdLR7Gw_YtXh28DYafL8L8RKdtWodzNVPH6KPx4f38XM2fX2ajEfTTDMhY1bUutZMCaFzDcrIsmxLI6FkRV3wpi0UFa2sFQDhudJUSWiAgRJA80ZBUfAhujn6br373KXrq5Xb-S6trJhM_0vOWZlY9MjS3oXgTVttvd0of6goqfrMqj-ZJQ07akLidgvjf53_F30DT9Rtdw</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Rao, Yunzhang</creator><creator>Huang, Tao</creator><creator>Tian, Changshun</creator><creator>Xiang, Cairong</creator><creator>Su, Gang</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230501</creationdate><title>Investigation on the Explosion Process and Chemical Activity of Pyrite Dust</title><author>Rao, Yunzhang ; Huang, Tao ; Tian, Changshun ; Xiang, Cairong ; Su, Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-7bcbc2a66c5c4ae899f9e84927b73df7a16f8ba44035ac1a84d424a6415da4773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemical activity</topic><topic>Chemical Kinetics and Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dust</topic><topic>Mathematical models</topic><topic>Numerical models</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Pyrite</topic><topic>Pyrrhotite</topic><topic>Sulfur oxides</topic><topic>Thermogravimetric analysis</topic><topic>Weight loss</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rao, Yunzhang</creatorcontrib><creatorcontrib>Huang, Tao</creatorcontrib><creatorcontrib>Tian, Changshun</creatorcontrib><creatorcontrib>Xiang, Cairong</creatorcontrib><creatorcontrib>Su, Gang</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rao, Yunzhang</au><au>Huang, Tao</au><au>Tian, Changshun</au><au>Xiang, Cairong</au><au>Su, Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation on the Explosion Process and Chemical Activity of Pyrite Dust</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>97</volume><issue>5</issue><spage>894</spage><epage>901</epage><pages>894-901</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The explosion process and chemical activity of pyrite dust were investigated by explosion test, thermo-gravimetric analysis and FactSage numerical simulation. Based on the results of tests and simulation of pyrite dust explosion, a numerical model was developed to reveal the explosion process. The results indicate that the explosion process is controlled by heterogeneous combustion and the volatilization of sulfur oxides leads to weight loss of pyrite dust. In addition, the explosion severity is dominated by the sulfur content, and the apparent activity energy of pyrite dust decreases with the sulfur content increasing, resulting in enhancing chemical activity and weight loss. 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subjects | Chemical activity Chemical Kinetics and Catalysis Chemistry Chemistry and Materials Science Dust Mathematical models Numerical models Oxidation Physical Chemistry Pyrite Pyrrhotite Sulfur oxides Thermogravimetric analysis Weight loss |
title | Investigation on the Explosion Process and Chemical Activity of Pyrite Dust |
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