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Blue emissive PVA blended cellulose nanocrystals/carbon dots film for UV shielding applications

The current state of ozone layer depletion caused by ultraviolet (UV) radiation and its impacts on human health and the environment make eco-friendly UV-blocking materials highly important. The present study reports an efficient, biodegradable film using polyvinyl alcohol (PVA) functionalized with c...

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Bibliographic Details
Published in:Cellulose (London) 2023-06, Vol.30 (9), p.5623-5639
Main Authors: Jose, Jasmine, Mathew, Raji Mary, Zachariah, Elsa Susan, Thomas, Vinoy
Format: Article
Language:English
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Summary:The current state of ozone layer depletion caused by ultraviolet (UV) radiation and its impacts on human health and the environment make eco-friendly UV-blocking materials highly important. The present study reports an efficient, biodegradable film using polyvinyl alcohol (PVA) functionalized with cellulose nanocrystals (CNCs) and carbon dots (CDs) that exhibits outstanding UV-blocking capabilities through blue light conversion. This study demonstrated an effective way for the clean and improved utilisation of waste paper by extracting CNCs from it and a green hydrothermal method employed for synthesising CDs from CNCs. The film composed of PVA blended with CNCs and CDs used in this work successfully blocked 99.7 UV-C, 98.5 UV-B, and 92.1% UV-A while transmitting 80.1% visible light. Furthermore, this film converted UV rays into blue light, indicating its sunlight conversion properties. High UV resistance, UV-to-blue light conversion capabilities, and excellent visible light transmission of these films make them a new contender among PVA-based UV-shielding and sunlight conversion materials.
ISSN:0969-0239
1572-882X
DOI:10.1007/s10570-023-05232-6